Sökning: "ligand synthesis"
Visar resultat 1 - 5 av 206 avhandlingar innehållade orden ligand synthesis.
1. Bispidine derivatives as molecular tools for studies of (-Allyl)palladium complexes : Ligand synthesis and analythical cpplications
Sammanfattning : Determination of structural and stereochemical features of reaction intermediates in transition metal catalysed reactions is of central interest. Bispidine derivatives as ligands in (π-allyl)palladium complexes in combination with 1H NMR spectroscopy are shown to be useful tools for revealing structural characteristics of these reaction intermediates. LÄS MER
Sammanfattning : This work focuses on the design, synthesis, characterization, and application projections of low-coordinated heavy pnictogen-containing (described by the generic letter E, hence E=C) phosphaalkenes (P=C) and arsaalkenes (As=C), with emphasis on the E=C group motifs. The work aims to understand their functional and modular character, reactivity, and potential applications by stabilizing, isolating, and characterizing these species in low-coordination environments. LÄS MER
3. The Synthesis of Molecular Switches Based Upon Ru(II) Polypyridyl Architecture for Electronic Applications
Sammanfattning : According to the famous axiom known as Moore’s Law the number of transistors that can be etched on a given piece of silicon, and therefore the computing power, will double every 18 to 24 months. For the last 40 years Moore’s prediction has held true as computers have grown more and more powerful. LÄS MER
4. Synthesis and application of β-configured [18/19F]FDGs : Novel prosthetic CuAAC click chemistry fluoroglycosylation tools for amyloid PET imaging and cancer theranostics
Sammanfattning : Positron emission tomography (PET) is a non-invasive imaging method that renders three-dimensional images of tissue that selectively has taken up a radiolabelled organic compound, referred to as a radiotracer. This excellent technique provides clinicians with a tool to monitor disease progression and to evaluate how the patient respond to treatment. LÄS MER
Sammanfattning : This thesis deals with the design and syntheses of chiral,enantiopure pyridinecontaining ligands and their applicationsin asymmetric catalyis.Chiral pyridyl pyrrolidine ligands and pyridyl oxazolineligands were synthesized and employed in thepalladium-catalysed allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate. LÄS MER