Sökning: "DBU"

Visar resultat 1 - 5 av 11 avhandlingar innehållade ordet DBU.

  1. 1. Functional and Modular As=C and P=C Group Motifs

    Författare :Daniel Morales Salazar; Andreas Orthaber; Jose Goicoechea; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; materials; physical chemistry; arsaalkenes; phosphaalkenes; DBU; fluorene; photochemistry; arsenic; phosphorus; carbon; hydrogen; sulfur; gold; copper; organic materials; organic electronics; molecular electronics; polymers; transition metal complexes; molecular materials; small molecule; hydrogen bonding; electrochemistry; cyclic voltammetry; chronoamperometry; electropolymerization; artificial intelligence; potentiodynamic; modularity; functionality; XPS; DFT; π-conjugation effects; 2D-NMR; disilenes; siliconoids; group motifs; functional group; emergence; reactivity; reactive systems; organometallic complexes; π-delocalization; low-coordinate; main group chemistry; heavy p-block elements; pnictogens; copper I complex; gold I complex; photosensitizer; XRD; spectroelectrochemistry; electrochromism; smart materials; synthesis; phosphaalkene ligands; imine ligands; hysteresis-like criteria; representative settings; optimal criteria; transient covalence; interactive image; conformer; isomer; ligand scrambling; nanomaterials; stimuli-responsive; optical properties; ligand design; molecular design; X-ray crystallography; emission; self-assembly; As=C; Si=Si; P=C; multiple bond; equilibrium; heteroalkenes; alkenes; reversibility; Raman; ATR-FTIR; ERDA; Kemi; Chemistry;

    Sammanfattning : This work focuses on the design, synthesis, characterization, and application projections of low-coordinated heavy pnictogen-containing (described by the generic letter E, hence E=C) phosphaalkenes (P=C) and arsaalkenes (As=C), with emphasis on the E=C group motifs. The work aims to understand their functional and modular character, reactivity, and potential applications by stabilizing, isolating, and characterizing these species in low-coordination environments. LÄS MER

  3. 2. Development of nitrogen-containing materials for capture and catalytic conversion of carbon dioxide to value-added chemicals

    Författare :Thai Q. Bui; Jyri-Pekka Mikkola; Knut Irgum; William Siljebo; Riitta Keiski; Umeå universitet; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; CCUS; PEHA; DBU; mesoporous melamine-formaldehyde; DMC; cyclic carbonate; flow reactor; Physical Chemistry; fysikalisk kemi; sustainable development; hållbar utveckling;

    Sammanfattning : Anthropogenic carbon dioxide (CO2) emissions have become a critical environmental issue because a large amount of CO2 releasing into the atmosphere, particularly from the massive use of fossil fuels, is the major factor promoting the global warming and climate change. To mitigate the CO2 emissions, Carbon Capture, Utilization and Storage (CCUS) can be one of important solutions. LÄS MER

  4. 3. Development of new Fluorination Methods Directed to Fluorine-18 Labelling

    Författare :Miguel Ángel Cortés González; Kálmán J. Szabó; Guosheng Liu; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; fluorine; fluorine-18; late-stage; labelling; nucleophilic; electrophilic; fluorination; positron emision tomography; PET; hypervalent iodine; benziodoxole; metal-free; DBU; copper; palladium; rhodium; carbene; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis deals with the development of new fluorination reactions and their application to fluorine-18 labelling. Fluorine-18 labelled compounds are employed as tracers in Positron Emission Tomography (PET), which is a powerful non-invasive imaging method in medical diagnostics. LÄS MER

  5. 4. Investigation of CO2 interactions with cellulose dissolved in the NaOH(aq) system

    Författare :Maria Gunnarsson; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; DBU; ATR-IR spectroscopy; NaOH aq ; dissolution; NMR spectroscopy; CO2; cellulose;

    Sammanfattning : Cellulose derived from wood can be used as raw material for production of textile fibres, making it a renewable alternative to fossil oil. One of the key steps in this process is dissolution of the cellulose. LÄS MER

  7. 5. Studies on Transformations of H-Phosphonates into DNA Analogues Containing P-S or P-C Bonds

    Författare :Tommy Johansson; Jacek Stawinski; Joachim Wolfgang Engels; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organic chemistry; Organisk kemi;

    Sammanfattning : In this thesis, mechanistic and synthetic studies on transformations of H-phosphonates into DNA analogues containing P-S or P-C bonds are described. Configurational stability of dinucleoside H-phosphonates and the stereochemical course of their sulfurisation in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) were investigated. LÄS MER