Sökning: "N-ligand"

Hittade 3 avhandlingar innehållade ordet N-ligand.

  1. 1. Chiral Pyridine-Containing Ligands for Asymmetric Catalysis. Synthesis and Applications

    Författare :Fredrik Rahm; KTH; []
    Nyckelord :asymmetric catalysis; chiral ligand; chiral pool; oxazoline; crown ether; ditopic receptor; bipyridine; pyridyl alcohol; modular approach; P; N-ligand; diethylzinc; allylic alkylation;

    Sammanfattning : This thesis deals with the design and syntheses of chiral,enantiopure pyridinecontaining ligands and their applicationsin asymmetric catalyis.Chiral pyridyl pyrrolidine ligands and pyridyl oxazolineligands were synthesized and employed in thepalladium-catalysed allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate. LÄS MER

  3. 2. Ligand Dependent Regioselectivity in Palladium Mediated Allylic Alkylation

    Författare :Charlotte Johansson; Göteborgs universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Palladium; allylic alkylation; η3-allyl palladium complexes; regioselectivity; PN-ligand; memory effects; dynamics; ligand effect; trans effects.;

    Sammanfattning : In this thesis, different aspects on ligand dependent regioselectivity in palladium mediated allylic alkylation have been studied. It is believed that the regioselectivity is a result of nucleophilic attack trans to phosphorous when applying ligands wih different donor atoms. LÄS MER

  4. 3. Flexibility – a tool for chirality control in asymmetric catalysis

    Författare :Raivis Zalubovskis; Christina Moberg; Alexandre Alexakis; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; flexibility; symmetry; dissymmetry; asymmetric catalysis; chiral ligands; pseudo-C2; pseudo-CS; conformational study; rotation barrier; pyrrolidines; phospholanes; azepines; phosphepines; supramolecular; hydrogenation; allylic alkylation; silaboration; palladium; rhodium; nickel; platinum; iridium.; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis deals with the design and synthesis of ligands for asymmetric catalysis: palladium catalyzed allylic alkylations, and rho-dium and iridium catalyzed hydrogenations of olefins. Chirally flexible phosphepine ligands based on biphenyl were synthesized and their properties were studied. LÄS MER