Sökning: "diethylzinc"

Visar resultat 1 - 5 av 6 avhandlingar innehållade ordet diethylzinc.

  1. 1. Chiral Pyridine-Containing Ligands for Asymmetric Catalysis. Synthesis and Applications

    Författare :Fredrik Rahm; KTH; []
    Nyckelord :asymmetric catalysis; chiral ligand; chiral pool; oxazoline; crown ether; ditopic receptor; bipyridine; pyridyl alcohol; modular approach; P; N-ligand; diethylzinc; allylic alkylation;

    Sammanfattning : This thesis deals with the design and syntheses of chiral,enantiopure pyridinecontaining ligands and their applicationsin asymmetric catalyis.Chiral pyridyl pyrrolidine ligands and pyridyl oxazolineligands were synthesized and employed in thepalladium-catalysed allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate. LÄS MER

  2. 2. C2- and C3-symmetric ligands via ring-opening of aziridines

    Författare :Fredrik Lake; KTH; []
    Nyckelord :asymmetric catalysis; aziridine; benzaldehyde; diethylzinc; enantionselective; ligand; proazaphosphatrane; ring-opening; sulfonamide; symmetry; titanium; nicronium;

    Sammanfattning : This thesis deals with the design and synthesis of chiralenantiopure nitrogencontaining ligands and the use of theseligands in asymmetric catalysis. A modular synthetic approachto enantiopure nitrogen-containing ligands was developed. Thesynthetic method is based on the ring-opening of activatedchiral aziridines by nitrogen nucleophiles. LÄS MER

  3. 3. Synthesis and evaluation of bicyclic 1,3-diols (BODOLs) as ligands for asymmetric catalysis

    Författare :Ian Sarvary; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organic chemistry; yeast reductions; supramolecular chemistry; diethylzinc; computation; structure of Ti-diolates; diol ligands; titanates; asymmetric catalysis; asymmetric synthesis;

    Sammanfattning : Several ligands based upon 2-substituted bicyclic[2.2.2]octane-2,6-diols (BODOLs) were synthesized and evaluated in two catalytic reactions: I) the Ti(IV)-mediated catecholborane asymmetric reduction of prochiral ketones and II) as catalysts in the asymmetric addition of diethylzinc to aromatic aldehydes. LÄS MER

  4. 4. Non Natural Aromatic Amino Acids Applications in cage-construction, metal ion coordination and asymmetric catalysis

    Författare :Ruxandra Ionescu; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; diethylzinc additions.; spectroscopy; metal ion coordination; cage-like compounds; Amino acids; C3-symmetry; Organic chemistry; Organisk kemi;

    Sammanfattning : Aromatic non-natural amino acids, the outstanding feature of which was the presence of several arms, were synthesised and their properties investigated. The amino acids were synthesised following a standard procedure starting with a Horner-Wadsworth-Emmons or a Heck reaction, which provided didehydroamino acids. LÄS MER

  5. 5. Synthesis of amino- and hydroxyl-substituted bridged bicyclic compounds and their application in asymmetric catalysis

    Författare :Cecilia Olsson; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; organocatalysis; asymmetric catalysis; bicyclo[2.2.1]heptane; bicyclo[2.2.2]octane; dibenzobicyclo[3.3.1]nonane; bioreduction; enzymatic kinetic resolution;

    Sammanfattning : In this work, hydroxyl- and amino-substituted bridged bicyclic compounds based on bicyclo[2.2.1]heptane, bicyclo[2.2. LÄS MER