Sökning: "influence of the mechanism of metal"

Visar resultat 6 - 10 av 78 avhandlingar innehållade orden influence of the mechanism of metal.

1. 6. Structure-Reactivity Correlations for Reactions of Palladium(II) and Platinum(IV) Complexes

   Författare :Tiesheng Shi; Kemiska institutionen; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; thiol; l-methionine; maleic acid; carboxylic acid; thioether; platinum IV ; palladium II ; linear free energy relationship; volumes of activation; structure-reactivity correlation; reduction; substitution; equilibria; kinetics; mechanism; glutathione; Animal physiology; Djurfysiologi;

   Sammanfattning : The kinetics and mechanism for substitution reactions on tetraaquapalladium(II) by an extended series of thioethers, a great number of carboxylic acids, and olefins have been studied by use of UV-VIS, stopped-flow, and high-pressure stopped-flow spectrophotometry and NMR spectroscopy. Second-order rate constants k and activation parameters (activation enthalpies, entropies, and volumes) for formation of monodentate 1:1 complexes have been determined. LÄS MER

3. 7. Technical development of the laser welding process

   Författare :Klas Nilsson; Luleå tekniska universitet; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Manufacturing Systems Engineering; Produktionsutveckling;

   Sammanfattning : This thesis describes the technical development of the laser welding process and presents the results from a number of experimental investigations. The seven papers that make up the thesis investigate various aspects of the technical development of the laser welding process mechanism as well as industrial applications. LÄS MER

4. 8. Transition metal-catalyzed reduction of carbonyl compounds : Fe, Ru and Rh complexes as powerful hydride mediators

   Författare :Elina Buitrago; Hans Adolfsson; Robert Morris; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Asymmetric catalysis; amino acid; N-heterocyclic carbene; iron; ruthenium; rhodium; mechanistic investigation; kinetic study; asymmetric transfer hydrogenation; hydrosilylation; organisk kemi; Organic Chemistry;

   Sammanfattning : A detailed mechanistic investigation of the previously reported ruthenium pseudo-dipeptide-catalyzed asymmetric transfer hydrogenation (ATH) of aromatic ketones was performed. It was found that the addition of alkali metals has a large influence on both the reaction rate and the selectivity, and that the rate of the reaction was substantially increased when THF was used as a co-solvent. LÄS MER

5. 9. Process development for investment casting of thin-walled components : Manufacturing of light weight components

   Författare :Mohsin Raza; Björn Fagerström; Jarfors Anders; Mälardalens högskola; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Investment casting; fluidity; thin sections; porosity; grain structure; turbine blades and Niyama criterion; Innovation and Design; innovation och design;

   Sammanfattning : Manufacturing processes are getting more and more complex with increasing demands of advanced and light weight engineering components, especially in aerospace industry. The global requirements on lower fuel consumption and emissions are increasing the demands in lowering weight of cast components. LÄS MER

7. 10. Characterization of Impurities in Different Ferroalloys and Their Effects on the Inclusion Characteristics of Steels

   Författare :Yong Wang; Pär Jönsson; Andrey Karasev; Bart Blanpain; KTH; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; ferroalloys; electrolytic extraction; metal surface; non-metallic inclusions; steel cleanliness; computational thermodynamics; ferrolegering; elektrolytisk extraktion; metallyta; icke-metalliska inneslutningar; stålrenhet; beräkningstermodynamik; Materials Science and Engineering; Teknisk materialvetenskap;

   Sammanfattning :      Ferroalloys have become increasingly important due to their indispensable role in steelmaking. As the performance requirements of steel materials increase, it is necessary to have a better understanding of the impact of impurities in ferroalloys on the steel cleanliness. LÄS MER