Sökning: "cage-like compounds"

Hittade 3 avhandlingar innehållade orden cage-like compounds.

1. 1. Non Natural Aromatic Amino Acids Applications in cage-construction, metal ion coordination and asymmetric catalysis

   Författare :Ruxandra Ionescu; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; diethylzinc additions.; spectroscopy; metal ion coordination; cage-like compounds; Amino acids; C3-symmetry; Organic chemistry; Organisk kemi;

   Sammanfattning : Aromatic non-natural amino acids, the outstanding feature of which was the presence of several arms, were synthesised and their properties investigated. The amino acids were synthesised following a standard procedure starting with a Horner-Wadsworth-Emmons or a Heck reaction, which provided didehydroamino acids. LÄS MER

3. 2. NMR Studies of Inclusion Compounds

   Författare :Sahar Nikkhou Aski; Jozef Kowalewski; Pierre Mutzenhardt; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NMR; 13C spin relaxation; PFGNMR; Kinetics; Correlation time; Physical chemistry; Fysikalisk kemi; Physical Chemistry; fysikalisk kemi;

   Sammanfattning : This thesis presents the application of some of the NMR methods in studying host-guest complexes, mainly in solution. The general focus of the work is on investigating the reorientational dynamics of some small molecules that are bound inside cavities of larger moieties. LÄS MER

4. 3. Synthesis of Indole Alkaloids and Development of New Methodology

   Författare :Anita Hoang; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; total synthesis; indole alkaloids; Domino reactions; vicinal quaternary stereocenters; quaternary stereocenter; indoline synthesis; communesin alkaloid; perophoramidine; dehaloperophoramidine; akuammiline alkaloids; strictamine; intramolecular Heck reaction; domino carbopalladation carbonylation; indoline alkaloids;

   Sammanfattning : This thesis describes our efforts towards the total synthesis of natural products and the development of a newmethodology to afford a synthetically important scaffold.Chapter 2 outlines our efforts towards the total synthesis of a marine natural product, perophoramidine as wellas our completed synthesis of dehaloperophoramidine. LÄS MER