Sökning: "structure of Ti-diolates"

Hittade 1 avhandling innehållade orden structure of Ti-diolates.

  1. 1. Synthesis and evaluation of bicyclic 1,3-diols (BODOLs) as ligands for asymmetric catalysis

    Författare :Ian Sarvary; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organic chemistry; yeast reductions; supramolecular chemistry; diethylzinc; computation; structure of Ti-diolates; diol ligands; titanates; asymmetric catalysis; asymmetric synthesis;

    Sammanfattning : Several ligands based upon 2-substituted bicyclic[2.2.2]octane-2,6-diols (BODOLs) were synthesized and evaluated in two catalytic reactions: I) the Ti(IV)-mediated catecholborane asymmetric reduction of prochiral ketones and II) as catalysts in the asymmetric addition of diethylzinc to aromatic aldehydes. LÄS MER