Sökning: "isomer pattern"

Visar resultat 1 - 5 av 8 avhandlingar innehållade orden isomer pattern.

1. 1. Sources of dioxins and other POPs to the marine environment : Identification and apportionment using pattern analysis and receptor modeling

   Författare :Kristina Sundqvist; Karin Wiberg; Mats Tysklind; Paul Geladi; Miriam Diamond; Umeå universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; air-water gas exchange; chiral; congener pattern; enantiomer; enantiomeric fraction; fugacity; HCH; hexachlorocyclohexane; homologue profile; indicator congener; isomer pattern; pattern analysis; PCA; PCB; PCDD F; PMF; polychlorinated dibenzofuran; polychlorinated dibenzo-p-dioxin; polychlorinated biphenyl; positive matrix factorization; principal component analysis; receptor modeling; source apportioning; source; source tracing; Environmental chemistry; Miljökemi; Persistent organic compounds; Persistenta organiska föreningar;

   Sammanfattning : In the studies underlying this thesis, various source tracing techniques were applied to environmental samples from the Baltic region. Comprehensive sampling and analysis of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in surface sediments in Swedish coastal and offshore areas resulted in a unique data set for this region. LÄS MER

3. 2. Thermal formation and chlorination of dioxins and dioxin-like compounds

   Författare :Stina Jansson; Stellan Marklund; Mats Tysklind; Jochen F. Müller; Umeå universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; dioxin; dioxin-like compounds; isomer distribution pattern; homologue profile; injection; O2PLS; PCDD; PCDF; PCN; PCBz; PCPh; MSW combustion; formation; chlorination; flue gas; quench profiles; Environmental chemistry; Miljökemi;

   Sammanfattning : This thesis contributes to an increased understanding of the formation of dioxins and dioxin-like compounds in combustion processes. Although emissions to air from waste incineration facilities have been greatly reduced by the use of efficient air pollution control measures, the resulting residues (ashes and filters) are highly toxic and are classified as hazardous waste. LÄS MER

4. 3. Synthesis and Rearrangement of Epoxy Sugars

   Författare :Fritiof Pontén; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organic chemistry; crown ether; silica; Intramoleculaf Diels-Alder reaction; radical allylation; allyl sulfone; sugar epoxide; allyl sulfide; ring-contraction; C-glycoside; a; IMDAF; b-unsaturated aldehyde;

   Sammanfattning : Ring-Contraction of sugar-derived epoxy alcohols, functionalised in position 1 and 6, by treatment with lithium bromide and N, N, N', N'-tetramethylurea in refluxing toluene gave enantiomerically pure a,b-unsaturated aldehydes of furanosides. O-Glycosidic epoxy alcohols gave only one, easily purified, aldehyde in approximately 30-60% yield depending on the substitution pattern. LÄS MER

5. 4. The Synthesis and Use of Certain Pyridine Derivatives as Modulators of the G-protein Coupled Receptors mGlu5 and P2Y12

   Författare :Peter Bach; Göteborgs universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; mGluR5; P2Y12; gastroesophageal reflux disease GERD ; thrombosis; ethyl nicotinates; ureas; sulfonylureas; oxazoles; bioisosteres; regioselectivity; solvent effect.;

   Sammanfattning : The glutamatergic mGlu5 receptor and the purinergic P2Y12 receptor are two important targets in the development of novel treatments of gastroesophageal reflux disease (GERD) and thrombosis, respectively. Synthesis was developed to investigate the structure-activity relationships (SAR) of a novel series of 2-alkynylpyridine derivatives as mGluR5 antagonists. LÄS MER

7. 5. A beta-phosphoglucomutase in carbohydrate metabolism of Lactococcus lactis

   Författare :Ny Qian; Teknisk mikrobiologi; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; mykologi; virologi; bakteriologi; Mikrobiologi; mycology; gene regulation; beta-phosphoglucomutase; maltose metabolism; lactate; metabolic engineering; alpha-phosphoglucomutase; Lactococcus lactis; Microbiology; virology; bacteriology; Biochemistry; Metabolism; Biokemi;

   Sammanfattning : Phosphoglucomutase (PGM) catalyzes the reversible conversion of glucose 1-phosphate to glucose 6-phosphate. Two distinct forms of PGM have been purifed and charactierized in Lactococcus lactis growing on maltose: one specific for the alpha-isomer, and the other specific for the beta-isomer of glucose 1-phosphate. LÄS MER