Sökning: "chlorination"

Visar resultat 1 - 5 av 36 avhandlingar innehållade ordet chlorination.

1. 1. Biomimetic Iron Complexes involved in Oxygenation and Chlorination : A Theoretical Study

   Författare :Holger Noack; Margareta R. A. Blomberg; Per E. M. Siegbahn; Martin Kaupp; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; biomimetic; iron; density functional theory; intradiol; chlorination; adpic acid; diamond core; reactivity; Bio-inorganic chemistry; Bio-oorganisk kemi; Theoretical chemistry; Teoretisk kemi; kemisk fysik; Chemical Physics;

   Sammanfattning : Biomimetic chemistry is directed towards the simulation of enzymatic reactivity with synthetic analogues. In this thesis a quantum chemical method has been employed to study the mechanism of highly reactive iron-oxo complexes involved in oxygenation and chlorination of organic substrates. LÄS MER

3. 2. Thermal formation and chlorination of dioxins and dioxin-like compounds

   Författare :Stina Jansson; Stellan Marklund; Mats Tysklind; Jochen F. Müller; Umeå universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; dioxin; dioxin-like compounds; isomer distribution pattern; homologue profile; injection; O2PLS; PCDD; PCDF; PCN; PCBz; PCPh; MSW combustion; formation; chlorination; flue gas; quench profiles; Environmental chemistry; Miljökemi;

   Sammanfattning : This thesis contributes to an increased understanding of the formation of dioxins and dioxin-like compounds in combustion processes. Although emissions to air from waste incineration facilities have been greatly reduced by the use of efficient air pollution control measures, the resulting residues (ashes and filters) are highly toxic and are classified as hazardous waste. LÄS MER

4. 3. Chlorine Cycling in Terrestrial Environments

   Författare :Malin Montelius; David Bastviken; Teresia Svensson; Katarina Abrahamsson; Linköpings universitet; []
   Nyckelord :LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Chloride; organic chlorine; chlorination; dechlorination; 36Cl; risk assessment modelling; Klorid; organiskt klor; klorering; deklorering; klor-36; riskmodellering;

   Sammanfattning : Chlorinated organic compounds (Clorg) are produced naturally in soil. Formation and degradation of Clorg affect the chlorine (Cl) cycling in terrestrial environments and chlorine can be retained or released from soil. LÄS MER

5. 4. Fundamental in-situ and ex-situ studies of energy storage related materials including different applications of voltammetry

   Författare :Ulrik Palmqvist; Patrice Millet; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Ni-Cd pocket plate batteries; b-Ni OH 2; b-NiOOH; failures; goethite; surface complexation; Pb II ; Zn II ; Cu II ; Cd II ; in-situ; carbon; nanostructured; voltammetry; X-ray diffraction; electrical test; potentiometry; TEM; chlorination; oorganisk kemi; Inorganic Chemistry;

   Sammanfattning : This thesis is a summary and discussion of eight papers dealing with failures and structural aspects of Ni-Cd industrial pocket plate batteries, applications of voltammetry in adsorption studies on goethite (a-FeOOH) surfaces and synthesis and characterisation of nanostructured carbons. The work consists of different areas of chemistry; electrochemistry, structural chemistry and solution chemistry. LÄS MER

7. 5. The relationship between fly ash chemistry and the thermal formation of polychlorinated pollutants during waste incineration

   Författare :Duong Ngoc Chau Phan; Stellan Marklund; Bogdan Dlugogorski; Umeå universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Incinerations; dioxins; PCDD Fs; PCBs; PCNs; flue gas; fly ash; sampling; particle characterization; XPS; XRD; SEM EDX; formation; chlorination; PCA; OPLS; OPLS-DA;

   Sammanfattning : The thermal formation of polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), biphenyls (PCBs), and naphthalenes (PCNs) is a major problem in waste incineration. Ideally, rather than relying on air cleaning systems and treatment techniques, their formation should be minimized or, if possible eliminated. LÄS MER