Sökning: "IMDAF"

Hittade 1 avhandling innehållade ordet IMDAF.

1. 1. Synthesis and Rearrangement of Epoxy Sugars

   Författare :Fritiof Pontén; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organic chemistry; crown ether; silica; Intramoleculaf Diels-Alder reaction; radical allylation; allyl sulfone; sugar epoxide; allyl sulfide; ring-contraction; C-glycoside; a; IMDAF; b-unsaturated aldehyde;

   Sammanfattning : Ring-Contraction of sugar-derived epoxy alcohols, functionalised in position 1 and 6, by treatment with lithium bromide and N, N, N', N'-tetramethylurea in refluxing toluene gave enantiomerically pure a,b-unsaturated aldehydes of furanosides. O-Glycosidic epoxy alcohols gave only one, easily purified, aldehyde in approximately 30-60% yield depending on the substitution pattern. LÄS MER