Sökning: "Pd catalysis"

Visar resultat 16 - 20 av 81 avhandlingar innehållade orden Pd catalysis.

1. 16. Impact of Secondary Interactions in Asymmetric Catalysis

   Författare :Anders Frölander; Christina Moberg; Gerard van Koten; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; asymmetric catalysis; secondary interaction; hydrogen bond; chiral ligand; allylic alkylation; hydrosilylation; cyanation; pymox; box; PHOX; pybox; palladium; iridium; rhodium; Lewis acid; Lewis base; Organic chemistry; Organisk kemi;

   Sammanfattning : This thesis deals with secondary interactions in asymmetric catalysis and their impact on the outcome of catalytic reactions. The first part revolves around the metal-catalyzed asymmetric allylic alkylation reaction and how interactions within the catalyst affect the stereochemistry. LÄS MER

3. 17. Self-adaptable catalysts : Importance of flexibility and applications in asymmetric catalysis

   Författare :Ester Fjellander; Christina Moberg; Jay Siegel; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; adaptable; flexible; semi-flexible; symmetry; conformational study; mechanistic study; rotation barrier; VT NMR; asymmetric catalysis; ligand design; allylic alkylation; hydrogenation; azepines; dioxaphosphepines; phosphepines; amines; phosphines; phosphoramidites; phosphinites; palladium; rhodium; Organic chemistry; Organisk kemi;

   Sammanfattning : The topic of this thesis is the design and synthesis of biaryl-based self adaptableligands for asymmetric metal catalysis. The results discussed in papers I-III are covered, together with some unpublished results concerning substrate-adaptable catalysts. A general survey of self-adaptable catalysts is presented first. LÄS MER

4. 18. Surface and Interface Phenomena Studied with Pd Metal-Oxide-semiconductor Structures : Adsorption, catalytic reactions, hydrogen sensing and Pd restructuring

   Författare :Mats Eriksson; Wolfgang Göpel; Linköpings universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

   Sammanfattning : The electronic properties of palladium metal-oxide-semiconductor (Pd-MOS) structures are highly sensitive to hydrogen over a large pressure range. Such devices have been found useful in several applications, e.g. as a chemical sensing element in the so called electronic nose. LÄS MER

5. 19. Near-ambient pressure velocity map imaging

   Författare :Tzu-En Chien; Dan Harding; Klas Engvall; Rainer Beck; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Catalyst; Surface reaction; Near-ambient pressure; CO; CO2; CO oxidation; Pd; Palladium; Instrument design; Velocity-map imaging; Katalysator; Ytreaktion; Näraomgivningstryck; CO; CO2; CO oxidation; Pd; Palladium; Instrumentdesign; Hastighetskartbildning; Chemical Engineering; Kemiteknik;

   Sammanfattning : Catalytic reactions on solid surfaces have been studied under Ultra-high vacuum (UHV) conditions for decades. These studies provide crucial information for catalytic reactions, such as surface structures, adsorption sites, and reaction mechanisms. LÄS MER

7. 20. Direct H2O2 synthesis over dilute PdAu alloys

   Författare :Rasmus Svensson; Chalmers tekniska högskola; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; kinetic Monte Carlo; H2O2 synthesis; metal-water interface; dynamics; kinetic modeling; dilute alloys; catalysis; density functional theory;

   Sammanfattning : Heterogeneous catalysis is crucial in a range of technological and industrial processes. Depending on the composition of the catalyst and the reaction conditions, it is possible to steer the activity and the selectivity towards the desired products. LÄS MER