Sökning: "Christina Moberg"

Visar resultat 1 - 5 av 12 avhandlingar innehållade orden Christina Moberg.

1. 1. Direct Amino Acid-Catalyzed Enantioselective α-Oxidation Reactions and Asymmetric de novo Synthesis of Carbohydrates

   Författare :Magnus Engqvist; Armando Cordova; Christina Moberg; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organo catalysis; Organic chemistry; Organisk kemi;

   Sammanfattning : The ability of amino acids to form nucleophilic enamines with aldehydes and ketones has been used in the development of asymmetric α-oxidation reactions with electrophilic oxidizing agents. Singlet molecular oxygen has for the first time been asymmetrically incorporated into aldehydes and ketones, and the products were isolated as their corresponding diols in good yields and ee’s. LÄS MER

3. 2. Isolation, Synthesis and Structure-Activity Relationships of Antifeedants against the Pine Weevil, Hylobius Abietis

   Författare :Carina Eriksson; Christina Moberg; John Pickett; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Pine weevil; Hylobius abietis; semiochemicals; antifeedant; feeding deterrent; feeding stimulant; bark extract; carboxylic acid; piperidine alkaloids; structure-activity; cinnamic aldehyde; benzaldehyde; Organic chemistry; Organisk kemi;

   Sammanfattning : The large pine weevil, Hylobius abietis L., is a major insect pest on conifer seedlings in northern Europe. Due to its feeding newly planted trees get girdled, resulting in high seedling mortality (up to 80%). As a consequence great financial losses to the forest industry occur. LÄS MER

4. 3. Self-adaptable catalysts : Importance of flexibility and applications in asymmetric catalysis

   Författare :Ester Fjellander; Christina Moberg; Jay Siegel; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; adaptable; flexible; semi-flexible; symmetry; conformational study; mechanistic study; rotation barrier; VT NMR; asymmetric catalysis; ligand design; allylic alkylation; hydrogenation; azepines; dioxaphosphepines; phosphepines; amines; phosphines; phosphoramidites; phosphinites; palladium; rhodium; Organic chemistry; Organisk kemi;

   Sammanfattning : The topic of this thesis is the design and synthesis of biaryl-based self adaptableligands for asymmetric metal catalysis. The results discussed in papers I-III are covered, together with some unpublished results concerning substrate-adaptable catalysts. A general survey of self-adaptable catalysts is presented first. LÄS MER

5. 4. Impact of Secondary Interactions in Asymmetric Catalysis

   Författare :Anders Frölander; Christina Moberg; Gerard van Koten; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; asymmetric catalysis; secondary interaction; hydrogen bond; chiral ligand; allylic alkylation; hydrosilylation; cyanation; pymox; box; PHOX; pybox; palladium; iridium; rhodium; Lewis acid; Lewis base; Organic chemistry; Organisk kemi;

   Sammanfattning : This thesis deals with secondary interactions in asymmetric catalysis and their impact on the outcome of catalytic reactions. The first part revolves around the metal-catalyzed asymmetric allylic alkylation reaction and how interactions within the catalyst affect the stereochemistry. LÄS MER

7. 5. Silaborations of Unsaturated Compounds

   Författare :Martin Gerdin; Christina Moberg; Kálmán Szabó; KTH; []
   Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; allylboration; bismetallation; boron; carbocyclization; catalysis; 1; 3-diene; enantioselective; 1; 6-enyne; interelement; N-heterocyclic carbene; nickel; palladium; phosphine; phosphoramidite; platinum; reaction mechanism; silaboration; silicon; silylborane; stereoselective; Chemistry; Kemi;

   Sammanfattning : This thesis deals with the development of transition metal-catalyzed silaborations of 1,3-dienes and 1,6-enynes. The first part of the thesis describes the development of the enantioselective 1,4-silaboration of 1,3-cyclohexadiene. A number of chiral metal-ligand complexes were evaluated. LÄS MER