Sökning: "Pd catalysis"
Visar resultat 21 - 25 av 81 avhandlingar innehållade orden Pd catalysis.
21. Atomic Layer Deposition and Immobilised Molecular Catalysts Studied by In and Ex Situ Electron Spectroscopy
Sammanfattning : The research work that I describe in my thesis deals with three different heterogenisation approaches for synthesising a heterogeneous transition metal catalyst used for direct C-H activation reactions. The three heterogenisation approaches considered in my research are: (1) heterogenisation of a molecular catalyst on a polymer support using covalent bonds, (2) heterogenisation of a catalyst on a reduced graphene oxide (rGO) support using non-covalent interactions and (3) immobilisation of a catalyst on an inorganic surface using covalent bonds and encapsulation in an inorganic matrix. LÄS MER
22. Novel strategies for C-C/X bond formation
Sammanfattning : The formation of C-C/X bonds is essential for the manufacture of a broad range of chemicals and materials used in areas critical for maintaining quality of life in modern society, e.g. pharmaceuticals, agrochemicals and polymers, and for aspects of research in organic chemistry. LÄS MER
23. Oxidation of some Late Transition Metal Surfaces: Structural Studies from UHV to Atmospheric Pressure
Sammanfattning : The oxidation of Rh, Pd and Pt is studied under conditions ranging from ultra high vacuum to ambient pressures, with emphasis on a complete understanding of the geometry of the various oxide structures found. The investigations use a combination of various experimental methods, including high resolution core level spectroscopy, low energy electron diffraction, surface x-ray diffraction and scanning tunneling microscopy, as well as density functional theory calculations. LÄS MER
24. On the Chemical Romance Between Gas and Surface, and how to Illuminate it
Sammanfattning : An increasing number of catalysis experiments are conducted at higher pressures to bridge the pressure gap. This means that we need to measure not only the sample surface but also the gas phase around the sample with spatial resolution. LÄS MER
25. Metallacyclic Phosphine Complexes and Intramolecular Csp3-H Bond Activation -Synthesis, Characterisation and Catalytic Application
Sammanfattning : The work presented in this thesis deals with metallacyclic late transition metal complexes, obtained by intramolecular Csp3-H activation, and the application of such compounds in catalysis. The new hemilabile P,O phosphines N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine (DPPAM), o-(diphenylphosphino)benzoic acid ethyl ester (DPPES), o-(diphenylphosphino)benzoic acid methyl ether (DPPET) and ±-1-(2- diphenylphosphino)phenylethyl propionate (±-DPPMES) and the symmetrical diphosphorus donor ligands cis-1,3-bis[(diphenylphosphino)methyl]-cyclohexane (DPCY), cis-1,3-bis[(di-tertbutylphosphino)methyl]cyclohexane (DTBCY) and cis-1,3-bis[(di-isopropylphosphino)methyl]cyclohexane (DIPCY) have been synthesised, allowing the preparation of a range of new metallacyclic rhodium(III), iridium(III) and palladium(II) complexes. LÄS MER
