Sökning: "reaction rate constant"

Visar resultat 1 - 5 av 63 avhandlingar innehållade orden reaction rate constant.

  1. 1. Chemometric methods for analysis of spectroscopic data from batch process monitoring

    Detta är en avhandling från Stockholm : Kemi

    Författare :Erik Furusjö; KTH.; [2001]
    Nyckelord :in situ spectroscopy; reaction monitoring; organic synthesis; solubility; crystallization; multivariate calibration; curve resolution; kinetic model; reaction rate constant; activation energy; target testing; bootstrap;

    Sammanfattning : Understanding of a process is essential for processdevelopment, optimisation and scale-up. In situ spectroscopy isan attractive measurement technique that can increase processunderstanding, since samples need not be retrieved from theprocess mixture. LÄS MER

  2. 2. On the Influence of Mixing and Scaling-Up in Semi-Batch Reaction Crystallization

    Detta är en avhandling från Stockholm : Kemiteknik

    Författare :Marika Torbacke; KTH.; [2001]
    Nyckelord :reaction crystallization; precipitation; benzoic acid; macromixing; mesomixing; micromixing; semi-batch; loop reactor; backmixing; colour experiments; scaling-up;

    Sammanfattning : Semi-batch crystallization experiments have been performedboth in a loop reactor and in stirred tank reactors.Hydrochloric acid was fed to a stirred solution of sodiumbenzoate, and benzoic acid immediately formed. Benzoic acid isformed in excess of the solubility making the solutionsupersaturated.The loop reactor is U-shaped. LÄS MER

  3. 3. Reaction-Diffusion kinetics of Protein DNA Interactions

    Detta är en avhandling från Uppsala : Acta Universitatis Upsaliensis

    Författare :Anel Mahmutovic; Uppsala universitet.; [2015]
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; umbrella sampling; molecular dynamics; RDME; PDE; sliding; intersegment transfer; hopping; sterics; intersegment transfer; Biology with specialization in Molecular Biotechnology; Biologi med inriktning mot molekylär bioteknik;

    Sammanfattning : Transcription factors need to rapidly find one specific binding site among millions of nonspecific sites on the chromosomal DNA. In this thesis I use various aspects of reaction-diffusion theory to investigate the interaction between proteins and DNA and to explain the searching, finding and binding to specific operator sites. LÄS MER

  4. 4. Radiation Induced Oxidative Dissolution of UO2

    Detta är en avhandling från Stockholm : KTH

    Författare :Ella Ekeroth; KTH.; [2006]
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; radiation; radiolysis; UO2; spent nuclear fuel; radicals; oxidants; reductants; rate constants; dissolution; H2O2; H2; TECHNOLOGY Chemical engineering Chemical process and manufacturing engineering Nuclear chemistry; TEKNIKVETENSKAP Kemiteknik Kemisk process- och produktionsteknik Kärnkemi;

    Sammanfattning : SammanfattningDenna doktorsavhandling berör oxidativ upplösning av UO2 (som modellsubstans för utbränt kärnbränsle) orsakad av radiolys av vatten samt effekten av H2 på denna denna process.Hastighetskonstanter för oxidation av UO2-pulver med olika oxidanter såsom H2O2 har bestämts experimentellt. LÄS MER

  5. 5. Determination of mercury chemical speciation in the presence of low molecular mass thiols and its importance for mercury methylation

    Detta är en avhandling från Umeå : Umeå universitet

    Författare :Van Liem-Nguyen; Umeå universitet.; [2016]
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Mercury; methylmercury; LMM thiol; mass spectrometry; biogeochemistry; soil; sediment; ICP; WinSGW; modeling; S XANES; ligand exchange; stability constant; boreal wetlands; Analytical Chemistry; analytisk kemi; Environmental Science; miljövetenskap;

    Sammanfattning : Methylmercury (MeHg) is a neurotoxic compound that threatens the well-being of humans and wildlife. It is formed through the methylation of inorganic mercury (HgII) under suboxic/anoxic conditions in soils, sediment and waters. LÄS MER