Sökning: "polymerization mechanism"

Visar resultat 1 - 5 av 49 avhandlingar innehållade orden polymerization mechanism.

  1. 1. Controlled Ring-Opening Polymerization : Mechanism and Synthesis of Macromolecular Architectures with Tailored Properties

    Författare :Maria Ryner; KTH; []
    Nyckelord :controlled ring-opening polymerization; poly L-lactide ; poly 1; 5-dioxepan-2one ; stannous octoate; tin alkoxide; DFT methods; mechanism; triblock; multiblock; tailored hydrophilicity; elastomers; resorbable materials;

    Sammanfattning : .... LÄS MER

  3. 2. Understanding the mechanisms behind atom transfer radical polymerization : exploring the limit of control

    Författare :Helena Bergenudd; Mats Jonsson; Eva Malmström Jonsson; David M Haddleton; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; polymerization; controlled radical polymerization; atom transfer radical polymerization; kinetics; catalysis; electrochemistry; Polymer chemistry; Polymerkemi;

    Sammanfattning : Atom transfer radical polymerization (ATRP) is one of the most commonly employed techniques for controlled radical polymerization. ATRP has great potential for the development of new materials due to the ability to control molecular weight and polymer architecture. LÄS MER

  4. 3. Quantum Chemical Studies of Protein-Bound Chromophores, UV-Light Induced DNA Damages, and Lignin Formation

    Författare :Bo Durbeej; Leif Eriksson; Tim Clark; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Quantum chemistry; quantum chemistry; calculations; density functional theory; excited states; photochemistry; chromophores; absorption spectra; bathochromic shift; isomerization; UV radiation; DNA damages; cycloaddition reactions; photoenzymic repair; electron transfer; lignin; polymerization; phenoxy radicals; dilignols; Kvantkemi; Quantum chemistry; Kvantkemi;

    Sammanfattning : Quantum chemical methods have been used to provide a better understanding of the photochemistry of astaxanthin and phytochromobilin; the photoenzymic repair of UV-light induced DNA damages; and the formation of lignin. The carotenoid astaxanthin (AXT) is responsible for the colouration of lobster shell. LÄS MER

  5. 4. Towards quinone/pEDOT conducting redox polymers as energy storage materials

    Författare :Huan Wang; Martin Sjödin; Xavier Crispin; Uppsala universitet; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; quinone; conducting redox polymer; doping; capacity; organic battery; polymerization;

    Sammanfattning : With the increased demand for electrical energy storage devices, e.g. electric vehicles and smart grids, organic batteries have caught increasing attention due to their advantages, such as sustainability, environmental friendliness and cheap raw materials over traditional inorganic energy storage materials. LÄS MER

  7. 5. Hydrophobic interactions of serpins

    Författare :Sabina Janciauskiene; Enheten för kroniska inflammatoriska och degenerativa sjukdomar; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Proteiner; enzymology; polymerization.; Proteins; conformational polymorphism; hydrophobic interaction; amyloid fibrils; Alzheimer`s peptide Ab; alpha-1-antichymotrypsin; C-terminal peptide; lithocholic acid; cholesterol; Key words: alpha-1-antitrypsin; bile acids; enzymologi;

    Sammanfattning : The proteins of the serpin family are primarily but not exclusively proteinase inhibitors, which share a common, similar structure. It is known that this structure undergoes major conformational changes upon cleavage in the serpin reactive site loop, and that these changes include rearrangements within the hydrophobic core of the molecule. LÄS MER