Sökning: "chemoselective"

Visar resultat 6 - 10 av 19 avhandlingar innehållade ordet chemoselective.

  1. 6. Flavins as Biomimetic Catalysts for Sulfoxidation by H2O2 : Catalyst Immobilization in Ionic Liquid for H2O2 Oxidations

    Författare :Auri Lindén; Jan-Erling Bäckvall; Peter Somfai; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; biomimetic; oxidation; catalysis; ionic liquid; hydrogen peroxide; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis deals with the development of catalytic oxidation reactions utilizing hydrogen peroxide as terminal oxidant. The main focus has been to find flavin catalysts that are easy to handle and stable to store but still able to perform the desired reaction. LÄS MER

  2. 7. Hyaluronan Based Biomaterials with Imaging Capacity for Tissue Engineering

    Författare :Yu Zhang; Dmitri Ossipov; Carsten Werner; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; hyaluronan; hydrogel; scaffold; tissue engineering; imaging; interpenetrating network; MRI; fluorescence imaging; scaffold degradation;

    Sammanfattning : This thesis presents the preparation of hyaluronan-based biomaterials with imaging capability and their application as scaffolds in tissue engineering. First, we have synthesized HA derivatives functionalized with different chemoselective groups. LÄS MER

  3. 8. Regioselective Heck Coupling Reactions : Focus on Green Chemistry

    Författare :Karl S. A. Vallin; Anders Hallberg; Mats Larhed; Walter Cabri; Uppsala universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Pharmaceutical chemistry; Farmaceutisk kemi; Pharmaceutical chemistry; Farmaceutisk kemi; Medicinal Chemistry; läkemedelskemi;

    Sammanfattning : Carbon-carbon bond formation reactions are among the most important processes in chemistry, as they represent key steps in the synthesis of more complex molecules from simple precursors. This thesis describes mainly the development of novel regioselective applications of the mild and versatile palladium-catalyzed carbon-carbon coupling method, commonly known as the Heck reaction. LÄS MER

  4. 9. New Methods for the Synthesis of 3-Substituted 1-Indanones : A Palladium-Catalyzed Approach

    Författare :Anna Arefalk; Anders Hallberg; Mats Larhed; Juan Carlos Carretero; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Heck; palladium; indanone; annulation; microwave heating; triflate; sulfinyl imine; HIV-1 protease inhibitor; Organisk kemi; Organic chemistry; Organisk kemi;

    Sammanfattning : In medicinal chemistry, there is a constant need for new preparative methods, both to make the synthesis process more effective, and to increase the accessibility to a wide variety of compounds. A number of different approaches can be used to attain these goals. LÄS MER

  5. 10. Synthetic and Mechanistic Studies with Iodine(III) Reagents

    Författare :Ester Maria Di Tommaso; Berit Olofsson; Marcos Suero; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; hypervalent iodine chemistry; organic synthesis; mechanistic studies; DFT; photocatalysis; Organic Chemistry; organisk kemi;

    Sammanfattning : This thesis describes the development of metal-free transformations and mechanistic studies on the reactivity of two classes of hypervalent iodine reagents: diaryliodonium salts and vinylbenziodoxolones (VBX). Recently, they have been recognized as valuable synthetic reagents with broad applicability in organic synthesis. LÄS MER