Sökning: "Peter Somfai"

Visar resultat 1 - 5 av 10 avhandlingar innehållade orden Peter Somfai.

  1. 1. Asymmetric [2,3]-Sigmatropic Rearrangement of Allylic Ammonium Ylides

    Författare :Jan Blid; Peter Somfai; James C. Anderson; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; asymmetric; [2; 3]-sigmatropic rearrangement; allylic amine; ammonium ylide; Lewis acid; enantioselective; boron; phosphazene base; NMR spectroscopy; DFT-calculations; Organic chemistry; Organisk kemi;

    Sammanfattning : The thesis describes the realization of an asymmetric [2,3]-sigmatropic rearrangement of achiral allylic amines. It is divided into two parts; the first part deals with the development of a Lewis acid-mediated [2,3]-sigmatropic rearrangement and the second the asymmetric version thereof. LÄS MER

  3. 2. Stereoselective Nucleophilic Additions to Aldehydes and Synthesis of α-Amino-β- Hydroxy-Esters

    Författare :Jakob Danielsson; Peter Somfai; Hans Adolfsson; Tobias Rein; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Asymmetric induction; stereochemical models; Mukaiyama; polar Felkin-Anh; Cornforth-Evans; 1; 3-dipole; aziridine; cycloaddition; amino alcohol; carbonylation; Heck reaction; quaternary stereocenter;

    Sammanfattning : This thesis deals with the development of new reaction methodology as well as stereochemical investigations. The first part concerns the investigation of 1,2- and merged 1,2- and 1,3- asymmetric induction in Mukaiyama aldol additions to α-heteroatom and α,β- heteroatom substituted aldehydes respectively. LÄS MER

  4. 3. New Methodologies in Organic Chemistry: Applications to the Synthesis of α-Amino Acids and Natural Products

    Författare :Sebastian Hirner; Peter Somfai; Varinder Aggarwal; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic synthesis; 2-Vinylaziridines; 3-Pyrrolines; Ringexpansion; Rearrangement; Anisomycin; Total synthesis; α-Amino acids; Arylglycines; Weinreb amides; α-Arylation; Grignard reagents; Umpolung; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis deals with the development and application of new synthetic methodology in organic chemistry. The first part describes the development of a new protocol for the synthesis of 3-pyrrolines by means of a microwave-assisted ring-expansion reaction of 2-vinylaziridines. LÄS MER

  5. 4. Flavins as Biomimetic Catalysts for Sulfoxidation by H2O2 : Catalyst Immobilization in Ionic Liquid for H2O2 Oxidations

    Författare :Auri Lindén; Jan-Erling Bäckvall; Peter Somfai; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; biomimetic; oxidation; catalysis; ionic liquid; hydrogen peroxide; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis deals with the development of catalytic oxidation reactions utilizing hydrogen peroxide as terminal oxidant. The main focus has been to find flavin catalysts that are easy to handle and stable to store but still able to perform the desired reaction. LÄS MER

  7. 5. Synthesis of Polyhydroxylated Surfactants : Comparison of Surfactant Stereoisomers and Investigation of Haemolytic Activity

    Författare :Kristina Neimert-Andersson; Peter Somfai; Krister Holmberg; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polyhydroxy surfactants; Sugar surfactants; Dihydroxylation; Metathesis; Langmuir monolayers; Chiral discrimination; Haemolysis; Organic chemistry; Organisk kemi;

    Sammanfattning : I den här avhandlingen har vi studerat hur man kan göra nya tensider. En tensid är en speciell molekyl som har förmågan att lösa sig i både vatten och olja. Man kan göra följande experiment hemma: Fyll en glasburk till hälften med vatten och tillsätt en droppe matolja. LÄS MER