Sökning: "Järn"

Visar resultat 31 - 35 av 129 avhandlingar innehållade ordet Järn.

  1. 31. Hydrogen diffusion and storage mechanisms in diopside

    Författare :Rickard Sundvall; Henrik Skogby; Alasdair Skelton; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Mineralogy; Mineralvetenskap; mineralogi; petrologi och geokemi; Mineralogy; Petrology and Geochemistry;

    Sammanfattning : Hydrogen is a widespread trace element in many nominally anhydrous minerals (minerals without water or hydroxyl ions in their structural formula) from the Earth's crust and mantle. The hydrogen is normally incorporated in the form of hydroxyl ions and can be regarded as structurally bound water. LÄS MER

  3. 32. Iron in Haem Biosynthesis. Structural Studies of Ferrochelatase and Frataxin

    Författare :Tobias Karlberg; Biokemi och Strukturbiologi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Naturvetenskap; Natural science; Molekylär biofysik; Molecular biophysics; Biomedicinska vetenskaper; Biomedical sciences; protein crystallography; ferrochelatase; haem biosynthesis; iron; frataxin;

    Sammanfattning : Ferrochelatase catalyses the synthesis of heme by inserting Fe(II) into protoporphyrin IX. The structure of ferrochelatase from yeast has been determined (2.4 Å). The structure is homodimeric with each of the monomer made up of two Rossmann type domains with an active-site cleft between them. LÄS MER

  4. 33. An Investigation of Peroxidase Activity in Biomimetic and Biological Systems

    Författare :Ekaterina Ryabova; Kemiska institutionen; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; metabolism; Metabolism; enzymologi; Proteiner; enzymology; Proteins; hemoglobin; catalysis; peptide; peroxidase; protoporphyrin IX; Biokemi; Biochemistry;

    Sammanfattning : In order to create a heme environment which permits biomimicry of heme-containing plant peroxidases and investigate the role played by the vinyl side chains of the porphyrin ring on the stability and, possibly, catalytic activity of model compounds, a number of new synthetic microperoxidases -– hemin-6(7)-gly-his methyl ester (HGH) and hemin-6(7)-gly-gly-his methyl ester (HGGH) and hemin-6,7-bis(gly-gly-his methyl ester) (H2GGH) as well as mesohemin-6(7)-gly-gly-his methyl ester (MGGH) and deuterohemin-6(7)-gly-gly-his methyl ester (DGGH) have been prepared by condensation of a peptide residue with the propionic side chains of hemin, mesohemin and deuterohemin, respectively. Reactivity studies towards different organic and inorganic substrates showed that not only five- but also six-coordinate hemin peptide complexes catalyze the oxidation of substrates by H2O2. LÄS MER

  5. 34. Iron based Li-ion insertion materials for battery applications

    Författare :Andreas Blidberg; Fredrik Björefors; Mats Johnsson; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Li-ion; battery; Li2FeP2O7; LiFeSO4F; PEDOT; Chemistry with specialization in Inorganic Chemistry; Kemi med inriktning mot oorganisk kemi;

    Sammanfattning : Li-ion batteries are currently the most efficient technology available for electrochemical energy storage. The technology has revolutionized the portable electronics market and is becoming a corner stone for large scale applications, such as electric vehicles. LÄS MER

  7. 35. A Study on Vanadium Extraction from Fe-V-P Melts Derived from Primary and Secondary Sources

    Författare :Mikael Lindvall; Du Sichen; Christiaan Pistorius; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; vanadium; V; V2O5; V2O3; ferrovanadium; vanadiferous; titaniferous; titanomagnetites; magnetite; spinel; slag; experimental; free; spinel; converter; LD; BOF; solubility; equilibrium; selective; oxidation; hibonite; karelianite; Al2O3; CaO; SiO2; Teknisk materialvetenskap; Materials Science and Engineering;

    Sammanfattning : Vanadium extraction methods were developed for iron-vanadium-phosphorus (Fe-V-P) melts derived from processing of V-bearing titanomagnetites and steel slags. Studies on phase relationships of V slags were carried out to provide important understanding of the extraction processes. LÄS MER