Sökning: "paramagnetic relaxation"

Visar resultat 1 - 5 av 31 avhandlingar innehållade orden paramagnetic relaxation.

  1. 1. Paramagnetic relaxation reagents : nuclear magnetic resonance studies of preferential solvation

    Författare :Hans Grahn; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : The interactions between neutral paramagnetic relaxation reagents (PARR's) and certain aromatic compounds have been studied by 1H and 13 C spin-lattice relaxation time measurements. In media such as cyclohexane and carbon tetrachloride, Cr(acac)3 becomes preferentially solvated by aromatic solutes. LÄS MER

  3. 2. Zero-Field Splitting in Gd(III) complexes : Towards a molecular understanding of paramagnetic relaxation

    Författare :Shehryar Khan; Michael Odelius; Arnold Maliniak; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Zero-Field Splitting; Relaxation; Quantum Chemistry; Molecular Dynamics; Gd III ; kemisk fysik; Chemical Physics;

    Sammanfattning : The prime objectives of contrast agents in Magnetic Resonance Imaging(MRI) is to accelerate the relaxation rate of the solvent water protons in the surrounding tissue. Paramagnetic relaxation originates from dipole-dipole interactions between the nuclear spins and the fluctuating magnetic field induced by unpaired electrons. LÄS MER

  4. 3. Probing Dynamics of Oligosaccharides by Interference Phenomena in NMR Relaxation

    Författare :Leila Ghalebani; Jozef Kowalewski; Norbert Mueller; Stockholms universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; NMR; sugars; oligosaccharides; carbon-13 relaxation; cross-correlated relaxation; molecular dynamics; internal motion; random jumps; PRE; paramagnetic relaxation; Chemistry; Kemi; fysikalisk kemi; Physical Chemistry;

    Sammanfattning : Oligosaccharides (carbohydrates) are a large class of biological molecules that are important as energy sources in the human body and have enormously varied biological functions. It is generally believed that biological activities of carbohydrates are related to their internal dynamics. LÄS MER

  5. 4. The paramagnetic Meissner effect

    Författare :Evie Papadopoulou; Uppsala universitet; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Materials science; high-temperature superconductivity; Bi-based compounds; paramagnetic Meissner effect; ageing; disordered magnets; chiral-glass; Materialvetenskap; Materials science; Teknisk materialvetenskap; Solid State Physics; fasta tillståndets fysik;

    Sammanfattning : The low field dynamics of some high temperature superconductors have been studied experimentally, using SQUID magnetometry. The research has been focused on the so called Paramagnetic Meissner Effect (PME), a phenomenon seen in some high temperature superconducting cuprates. LÄS MER

  7. 5. Water Relaxation Processes as Seen by NMR Spectroscopy Using MD and BD Simulations

    Författare :Ken Åman; Per-Olof Westlund; Arnold Maliniak; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; NMR; Stochastic Liouville Equation; Brownian Dynamics; Molecular Dynamics; Water; Relaxation; Deuterium; ESR; Fysikalisk kemi; Physical chemistry; Fysikalisk kemi; Physical Chemistry; fysikalisk kemi;

    Sammanfattning : This thesis describes water proton and deuterium relaxation processes, as seen by Nuclear Magnetic Resonance (NMR) spectroscopy, using Brownian Dynamics (BD) or Molecular Dynamics (MD) simulations. The MD simulations reveal new detailed information about the dynamics and order of water molecules outside of a lipid bilayer. LÄS MER