Sökning: "interaction kinetics"

Visar resultat 11 - 15 av 196 avhandlingar innehållade orden interaction kinetics.

  1. 11. Chloromethane Complexation by Cryptophanes : Host-Guest Chemistry Investigated by NMR and Quantum Chemical Calculations

    Författare :Zoltan Takacs; Jozef Kowalewski; Mikael Akke; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Host–guest complexes; inclusion phenomenon; cryptophanes; NMR; kinetics; activation energy; dipolar interaction; exchange; quantum chemical optimization; calculated chemical shifts; NOESY; cavity size; fysikalisk kemi; Physical Chemistry;

    Sammanfattning : Host–guest complexes are widely investigated because of their importance in many industrial applications. The investigation of their physico–chemical properties helps understanding the inclusion phenomenon. The hosts investigated in this work are cryptophane molecules possessing a hydrophobic cavity. LÄS MER

  2. 12. Diastereomeric Effects in DNA Binding – Biological and Biophysical Studies on Ruthenium Complexes

    Författare :Anna Mårtensson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; neighbor interaction; spectroscopy; diastereomeric; kinetics; antimicrobial activity; ruthenium; calorimetry; intercalation; DNA; enantiomer;

    Sammanfattning : Organic molecules, such as glucose and amino acids, are most often chiral. This means that their mirror-images are different, in the same way a left and a right hand are different from each other. For example, the DNA double helix in its standard form twists like a right-handed screw. LÄS MER

  3. 13. Amyloid beta aggregation kinetics : The role of intrinsic and extrinsic factors

    Författare :Xiaoting Yang; Biokemi och Strukturbiologi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Alzheimer s disease; Abeta; aggregation; kinetics; secondary nucleation;

    Sammanfattning : Cerebral senile plaque is one of the main pathologies of Alzheimer's disease (AD). The amyloid cascade hypothesis suggests that the aggregation of amyloid beta (Abeta) peptide is involved in the pathogenesis of AD, which is supported by the fact that Abeta overexpression or production of more aggregation-prone variants lead to early-onset dementia. LÄS MER

  4. 14. Characterization of Carbon Oxidation Kinetics for Particulate Matter Reduction Technologies

    Författare :Carolin Ohlson; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Heterogeneous catalysis; Carbon – catalyst interaction; Soot oxidation; Particulate filter; Carbon oxidation; Global kinetics; Regeneration; Particulate matter oxidation; DPF;

    Sammanfattning : Transport related emissions of particulate matter (PM) represent a significant health risk and are therefore strictly regulated in most developed countries. An efficient technique to reduce emissions of combustion particles is to capture the particles in a filter, which must be subsequently regenerated by oxidation of the carbonaceous fraction of the PM. LÄS MER

  5. 15. Formation and Decomposition of Platinum–Thallium Bond, Kinetics and Mechanism. Structural Characterization of Some Metal Cyanides in the Solid State

    Författare :Péter Nagy; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; metal–metal bond; platinum; thallium; kinetics; mechanism; stopped flow; oxidative addition; cyano complexes; edta; redox reaction; metal cyanides; X–ray diffraction; Raman; NMR; mercury; palladium; nickel; one dimensional wire;

    Sammanfattning : The kinetic and mechanistic features of a new series ofplatinum-thallium cyano compounds containing a direct andunsupported by ligands metal-metal bond have been studied insolution, using standard mix–and–measurespectrophotometric technique and stopped–flow method.These reactions are interpreted as oxidative addition of the cspecies to the square planar Pt(CN)42-complex. LÄS MER