Sökning: "diastereomeric"

Visar resultat 1 - 5 av 26 avhandlingar innehållade ordet diastereomeric.

  1. 1. Diastereomeric Effects in DNA Binding – Biological and Biophysical Studies on Ruthenium Complexes

    Författare :Anna Mårtensson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; neighbor interaction; spectroscopy; diastereomeric; kinetics; antimicrobial activity; ruthenium; calorimetry; intercalation; DNA; enantiomer;

    Sammanfattning : Organic molecules, such as glucose and amino acids, are most often chiral. This means that their mirror-images are different, in the same way a left and a right hand are different from each other. For example, the DNA double helix in its standard form twists like a right-handed screw. LÄS MER

  3. 2. Chiral Recognition by Means of Mass Spectrometry

    Författare :Oleksii Rebrov; Mats Larsson; Per Johnsson; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chirality; Mass spectrometry; Chiral recognition; Gas phase; kemisk fysik; Chemical Physics;

    Sammanfattning : This thesis is based on experimental studies of chiral ions in gas-phase. Electrospray ion source platform (Stockholm University) and commercially available Quadrupole Time-of-Flight mass spectrometer have been used in our studies. LÄS MER

  4. 3. Interactions of chiral ions and molecules in gas phase : Towards an understanding of chiral recognition mechanism

    Författare :Oleksii Rebrov; Mats Larsson; Richard Thomas; Vitali Zhaunerchyk; Anne Zehnacker-Rentien; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; fysik; Physics;

    Sammanfattning : This thesis comprises the research related to interactions of enantiopure amino acids with chiral and achiral molecules in gas phase. The investigation of the mechanism responsible for chiral discrimination is of the special interest in this work. LÄS MER

  5. 4. 1. Asymmetric aldol and alkylation reactions using pyrrolidine-based chiral auxiliaries 2. Syntheses of pine sawfly pheromone precursors and structurally related compounds

    Författare :Fredrik Andersson; KTH; []
    Nyckelord :Chiral auxiliary; Stereoselectivity; Lewis acid; Aldol; Alkylation; Sex pheromone; Pine sawfly; Lipase; Synthesis; Diprion nipponica; Macrodiprion memoralis; Microdiprion pallipes; ;

    Sammanfattning : This thesis describes the syntheses of the 1-propionylatedauxiliaries (S)-(− )-2-(pyrrolidin-2-yl)propan-2-ol and (S)-(− )-2-(1-methoxy-1-methylethyl)pyrrolidine andtheir use in asymmetric aldol and alkylation reactions. Thesynthesis of 1-propionylated (2S,4R) 2-{4-[(tert-butyldimethylsilyl)oxy]pyrrolidin-2-yl}propan-2-olis also described. LÄS MER

  7. 5. Development of new Catalytic Methods for the Selective Synthesis of Heterocycles

    Författare :Stalin Reddy Pathi Pati; Nicklas Selander; Masaharu Nakamura; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; catalysis; indium; heterocycles; Lewis acid; multicomponent reactions; furans; alkynes; organisk kemi; Organic Chemistry;

    Sammanfattning : In the field of organic chemistry, the development of new catalytic methods for the synthesis of complex molecules from simple precursors is a top priority. The main focus of this thesis concerns the diastereoselective synthesis of heterocyclic compounds using main group elements as Lewis acid catalysts. LÄS MER