Sökning: "hydrogen oxide systems"

Visar resultat 6 - 10 av 49 avhandlingar innehållade orden hydrogen oxide systems.

1. 6. Reactions of aqueous radiolysis products with oxide surfaces : An experimental and DFT study

   Författare :Cláudio Miguel Lousada Patrício; Mats Jonsson; Jean-Philippe Renault; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; hydrogen peroxide; hydrogen production; metal; oxides; lanthanide; catalysis; density functional theory; surface; reactions; chemistry; SRA - Energy; SRA - Energi; SRA - Production; SRA - Produktion;

   Sammanfattning : The reactions between aqueous radiolysis products and oxide surfaces are important in nuclear technology in many ways. In solid-liquid systems, they affect (and at the same time are dependent on) both the solution chemistry and the stability of materials under the influence of ionizing radiation. LÄS MER

3. 7. Experimental studies of radiation-induced dissolution of UO2 : The effect of intrinsic solid phase properties and external factors

   Författare :Alexandre Barreiro Fidalgo; Mats Jonsson; David Shoesmith; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Oxidation; dissolution; uranium dioxide; gadolinium; bentonite; sulfide; hydrogen; gamma radiation; radiolysis; hydrogen peroxide; hydroxyl radical; repository; Kemi; Chemistry;

   Sammanfattning : Dissolution of the UO2 matrix is one of the potential routes for radionuclide release in a future deep geological repository for spent nuclear fuel. This doctoral thesis focuses on interfacial reactions of relevance in radiation-induced dissolution of UO2 and is divided in two parts:In the first part, we sought to explore the effects of solid phase composition:The impact of surface stoichiometry on the reactivity of UO2 towards aqueous radiolytic oxidants was studied. LÄS MER

4. 8. Nanoparticle Plasmons in Classic and Novel Materials - Fundamentals and Hydrogen Sensing

   Författare :Christoph Langhammer; Chalmers tekniska högskola; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; nanoparticle; hydrogen storage; aluminum; hydrogen sensing; localized surface plasmon resonance; platinum; nanostructure; palladium; nanoparticle plasmon;

   Sammanfattning : The interaction of light with sub-wavelength noble metal nanoparticles and nanostructures has developed into one of the most vibrant themes of nanoscience during the past decade. The optical properties of metal nanoparticles are dominated by so-called nanoparticle plasmons or localized surface plasmon resonances (LSPR). LÄS MER

5. 9. Hydrogen in oxides: a density-functional study of thermodynamic and kinetic aspects

   Författare :Mårten Björketun; Chalmers tekniska högskola; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; proton conduction; La$_2$Zr$_2$O$_7$; protonation; kinetic Monte Carlo; density functional theory.; BaZrO$_3$; hydrogen oxide systems; electronic structure;

   Sammanfattning : Many solid oxides, especially those possessing a perovskite structure, exhibit significant proton conductivity when being acceptor doped and placed in hydrogen-containing atmospheres. Consequently, they have attracted attention foruse as solid membranes in electrochemical devices such as gas sensors, steam electrolyzers and fuel cells. LÄS MER

7. 10. Innovations in nanomaterials for proton exchange membrane fuel cells

   Författare :Robin Sandström; Thomas Wågberg; Ludvig Edman; Florian Nitze; Licheng Sun; Umeå universitet; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; Fuel Cells; Membrane Electrode Assembly; Oxygen Reduction Reaction; Platinum alloy catalyst; Nanoparticles; Gas Diffusion Electrode; Proton Exchange Membrane; Materials Science; materialvetenskap; fasta tillståndets fysik; Solid State Physics;

   Sammanfattning : Hydrogen technologies are rapidly receiving increased attention as it offers a renewable energy alternative to the current petroleum-based fuel infrastructure, considering that continued large-scale use of such fossil fuels will lead to disastrous impacts on our environment. The proton exchange membrane fuel cell should play a significant role in a hydrogen economy since it enables convenient and direct conversion of hydrogen into electricity, thus allowing the use of hydrogen in applications particularly suited for the transportation industry. LÄS MER