Sökning: "electrospray ionization"

Visar resultat 31 - 35 av 84 avhandlingar innehållade orden electrospray ionization.

  1. 31. Microscale Tools for Sample Preparation, Separation and Detection of Neuropeptides

    Författare :Andreas Dahlin; Jonas Bergquist; Karin E. Markides; Robert T. Kennedy; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Analytical chemistry; Neuropeptides; Microchip; Enhanced microdialysis; Poly dimethylsiloxane PDMS ; Electrospray ionization ESI ; Multidimensional separation; Electrochemical manipulation; Mass spectrometry MS ; Capillary electrophoresis CE ; Microdevice; Microfabrication; Micro total analysis system μ-TAS ; Analytisk kemi; Analytical chemistry; Analytisk kemi;

    Sammanfattning : The analysis of low abundant biological molecules is often challenging due to their chemical properties, low concentration and limited sample volumes. Neuropeptides are one group of molecules that fits these criteria. Neuropeptides also play an important role in biological functions, which makes them extra interesting to analyze. LÄS MER

  3. 32. Experimental studies of cluster ions containing water, ammonia, pyridine and bisulphate

    Författare :Mauritz Johan Ryding; Göteborgs universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; clusters; ions; water; ammonia; pyridine; bisulphate; cross sections; collision induced dissociation CID ; kinetic modelling; electrospray ionization ESI ; time-of-flight TOF ; mass spectrometry;

    Sammanfattning : Molecular cluster ions are fascinating subjects of study. Bridging the size gap between molecules and bulk, they often display non-trivial size dependent behaviour and properties. LÄS MER

  4. 33. Palladium(II)-Catalysed Heck and Addition Reactions : Exploring Decarboxylative and Desulfitative Processes

    Författare :Bobo Skillinghaug; Mats Larhed; Antonio de la Hoz Ayuso; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Palladium; catalysis; palladium II catalysis; synthesis; Heck; carboxylic acid; sulfinic acid; sodium sulfinate; nitrile; styrene; ketone; aryl ketone; electrospray ionization mass spectrometry; density functional theory; microwave heating; continuous flow; Chemistry with specialization in Organic Chemistry; Kemi med inriktning mot organisk kemi;

    Sammanfattning : Palladium complexes have the ability to catalyse cross-coupling of two organic moieties through the formation of transient metal-carbon bonds, thus bringing them closer to each other to facilitate the formation of a new bond. Palladium-catalysed coupling reactions are one of the most important carbon-carbon forming reactions available to organic chemists and many of these reactions rely on the reactivity of aryl-palladium complexes. LÄS MER

  5. 34. Advances in analytical methodologies for studies of the platinum metallome in malignant cells exposed to cisplatin

    Författare :Yvonne Nygren; Erik Björn; Knut Irgum; Bente Gammelgaard; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Method development; Metallome; Inductively coupled plasma mass spectrometry; Electrospray ionization mass spectrometry; Liquid chromatography; Hyphenation; Organic modifier; Cisplatin; Platinum; Analytical chemistry; Analytisk kemi; analytisk kemi; Analytical Chemistry;

    Sammanfattning : The scientific progress about the important chemotherapeutic drug substance cisplatin (CDDP) and its function has often been rendered by data difficult to interpret, and still many questions about its mode of action remains to be clarified by the scientific community. However, studies of CDDP possess a high complexity due to; i) low intracellular concentration, ii) many potential biomolecule targets, iii) poor or unknown stability of the intact drug and its biomolecule adducts and iv) complex and varying sample matrices. LÄS MER

  7. 35. Tetradentate amide extraction agents for trivalent lanthanides

    Författare :Mikhail S Tyumentsev; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; malonamides; lanthanides; solvent extraction; entropic effect; electrospray ionization – mass spectrometry; single-crystal X-ray diffraction;

    Sammanfattning : Lanthanides are valuable materials. They are used in catalysts, permanent magnets, batteries, optical devices, and in many other products. Lanthanides are mainly supplied by mining industry, which generates large volumes of waste due to relatively low concentrations of these elements in geological deposits. LÄS MER