Sökning: "radiolys"

Visar resultat 1 - 5 av 8 avhandlingar innehållade ordet radiolys.

  1. 1. Stability of UO2 in systems containing radiolytic oxidants : The role of uranyl peroxide species

    Författare :Junyi Li; Mats Jonsson; Peter Burns; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; UO2; studtite; XPS; radiolysis; UO2; studtit; XPS; radiolys; Kemi; Chemistry;

    Sammanfattning : Nuclear power constitutes a major pillar on the global energy market, and it will most probably increase in importance as fossil fuels are gradually phased out. The main problem connected to nuclear power is the generation of highly radiotoxic spent nuclear fuel (95% UO2 and 5% radioactive fission products and heavier actinides). LÄS MER

  3. 2. Stability of Alternative Nuclear Fuel Materials in Aqueous Systems

    Författare :Sawsan El Jamal; Mats Jonsson; Mats Johnsson; Claire Corkhill; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; UC; UN; UO2; gamma radiolysis; oxidative dissolution; H2O2; studtite; additive; UC; UN; UO2; gammaradiolys; oxidativ upplösning; H2O2; studtite; additiv; Kemi; Chemistry;

    Sammanfattning : Nuclear power produces a large portion of the electricity worldwide. It has been the largest low-carbon energy source for more than 30 years and has played an essential role in the security of energy supplies for many countries. LÄS MER

  4. 3. Radiation-Induced Damage Processes in Nuclear Reactor Environments

    Författare :Elin Toijer; Pär Olsson; Julie Tucker; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Fysik; Physics;

    Sammanfattning : It is essential that the materials used in nuclear reactor applications maintain their structural integrity. However, consequences of the strong radiation field in the reactor core include radiolysis of the water surrounding the materials, as well as direct defect generation in the material itself. LÄS MER

  5. 4. Radiation Induced Oxidative Dissolution of UO2

    Författare :Ella Ekeroth; Mats Jonsson; Bernd Grambow; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; radiation; radiolysis; UO2; spent nuclear fuel; radicals; oxidants; reductants; rate constants; dissolution; H2O2; H2; Nuclear chemistry; Kärnkemi;

    Sammanfattning : Sammanfattning Denna doktorsavhandling berör oxidativ upplösning av UO2 (som modellsubstans för utbränt kärnbränsle) orsakad av radiolys av vatten samt effekten av H2 på denna denna process. Hastighetskonstanter för oxidation av UO2-pulver med olika oxidanter såsom H2O2 har bestämts experimentellt. LÄS MER

  7. 5. Redox Reactions of Uranium-Based Materials in Aqueous Systems and Under UHV Conditions. : Two models mimicking radiation-induced oxidation of spent nuclear fuel

    Författare :Ghada El Jamal; Mats Jonsson; Christophe Jégou; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Kemi; Chemistry;

    Sammanfattning : The demand for clean electricity is a primary concern in Europe. Nuclear power isconsidered as a greenhouse gas-free technology for generation of electricity. However,compared to other energy sources, it generates a highly toxic waste.In Sweden, the long-term solution for the waste disposal issue is called the KBS-3 method. LÄS MER