Sökning: "nickel complexes"
Visar resultat 6 - 10 av 26 avhandlingar innehållade orden nickel complexes.
6. Sintering of nickel catalysts in the presence of NH3/H2
Sammanfattning : Supported metal catalysts are used in many important industrial processes, where amination of alcohols is one example. The exposure of the supported metal catalyst to reaction conditions results usually to a decrease in catalytic activity, by for instance thermal degradation. LÄS MER
7. Formation and Decomposition of Platinum–Thallium Bond, Kinetics and Mechanism. Structural Characterization of Some Metal Cyanides in the Solid State
Sammanfattning : The kinetic and mechanistic features of a new series ofplatinum-thallium cyano compounds containing a direct andunsupported by ligands metal-metal bond have been studied insolution, using standard mixandmeasurespectrophotometric technique and stoppedflow method.These reactions are interpreted as oxidative addition of the cspecies to the square planar Pt(CN)42-complex. LÄS MER
8. Artificial Photosynthesis: Molecular Catalysts for Water Oxidation
Sammanfattning : Artificial photosynthesis provides a promising solution to the future sustainable energy system. Water is the only suitably sufficient protons and electrons supplier by the reaction of water oxidation. However, this reaction is both kinetically and thermodynamically demanding, leading to a sluggish kinetics unless the introduction of a catalyst. LÄS MER
9. Mechanistic Studies of Dinuclear Metalloenzymes - A Model Approach
Sammanfattning : With the goal to study the mechanisms of dinuclear metalloenzymes, a new line of synthetic and computational models were prepared and studied. Mixed imidazole and carboxylate multidentate complexes were synthesized to better simulate carboxylate-rich ligand environments. LÄS MER
10. Sorption and weathering properties of naturally occurring chlorites
Sammanfattning : Chlorite is a ferrous silicate mineral occurring as afracture filling mineral in the Swedish granite bedrock thatsurrounds the area of the candidate Swedish geologicalrepositories for nuclear waste. To investigate the importance of chlorites as a naturalbarrier for radionuclide migration sorption of Ni(II) onto anatural chlorite was chosen as the studied system. LÄS MER