Sökning: "cyclometallation"

Visar resultat 1 - 5 av 7 avhandlingar innehållade ordet cyclometallation.

1. 1. C–H activation through late transition metal cyclometallation. Addressing selectivity and reactivity problems

   Författare :Mikhail Kondrashov; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; C—H activation; cyclometallation; pincer ligands; anion exchange; bimetallic complexes; oxidative functionalisation;

   Sammanfattning : The ligand-directed C—H activation relies on a coordinating donor atom being in proximity to the C—H bond activated. Cyclometallation of 2-(1-naphthyl)-pyridine – a substrate containing both γ- and δ-positions in proximity to the directing nitrogen atom – was studied. LÄS MER

3. 2. Unsymmetric PCN Pincer Palladium and Nickel Complexes : Synthesis, Characterization and Reactivity

   Författare :Abdelrazek Mousa; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Unsymmetric PCN; Palladium; Nickel; Cyclometallation; Carboxylation; Cross-coupling;

   Sammanfattning : New palladium and nickel complexes based on unsymmetric PCN pincer ligands have been synthesized and fully characterized using different techniques. The substituents on the nitrogen side arm of the ligand have great influence on the cyclometallation and the reactivity of the new complexes particularly in case of nickel. LÄS MER

4. 3. Reactivity of late transition metal complexes towards CO2 and other electrophiles

   Författare :Magnus Johnson; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; CO2; carbon dioxide; electrophiles; late transition metal complexes; catalysis; halogen bonding; XB; cyclometallation; pincer; organometallic synthesis;

   Sammanfattning : In times when dwindling energy resources is a major long-term problem for sustaining modern infrastructure and technologies, we need to focus on more enduring solutions. A key contribution to this achievement is catalysis. LÄS MER

5. 4. Nickel and iridium pincer complexes with saturated frameworks - synthesis and reactivity

   Författare :Klara Jonasson; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; PCP complexes; aliphatic pincer ligands; coordination; cyclometallation; iridium; nickel; organometallic synthesis; CO2 activation; catalysis;

   Sammanfattning : As the tridentate chelate complexes referred to as pincer complexes have expanded their scope as homogeneous catalysts, there is an increased interest in electronic and steric fine-tuning of such complexes. One accessible variable in this aspect is the hybridisation of any coordinated carbon atoms. LÄS MER

7. 5. Metallacyclic Phosphine Complexes and Intramolecular Csp3-H Bond Activation -Synthesis, Characterisation and Catalytic Application

   Författare :Sven Sjövall; Kemiska institutionen; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; catalysis; Heck; diphosphite; diphosphine; phosphine; cyclometallation; C-C activation; C-O activation; C-H activation; palladium; rhodium; iridium; Inorganic chemistry; Oorganisk kemi;

   Sammanfattning : The work presented in this thesis deals with metallacyclic late transition metal complexes, obtained by intramolecular Csp3-H activation, and the application of such compounds in catalysis. The new hemilabile P,O phosphines N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine (DPPAM), o-(diphenylphosphino)benzoic acid ethyl ester (DPPES), o-(diphenylphosphino)benzoic acid methyl ether (DPPET) and ±-1-(2- diphenylphosphino)phenylethyl propionate (±-DPPMES) and the symmetrical diphosphorus donor ligands cis-1,3-bis[(diphenylphosphino)methyl]-cyclohexane (DPCY), cis-1,3-bis[(di-tertbutylphosphino)methyl]cyclohexane (DTBCY) and cis-1,3-bis[(di-isopropylphosphino)methyl]cyclohexane (DIPCY) have been synthesised, allowing the preparation of a range of new metallacyclic rhodium(III), iridium(III) and palladium(II) complexes. LÄS MER