Sökning: "Karin Leijondahl"

Hittade 1 avhandling innehållade orden Karin Leijondahl.

  1. 1. Synthesis and asymmetric transformations of diols by enzyme- and ruthenium catalysis

    Författare :Karin Leijondahl; Jan-Erling Bäckvall; Kurt Faber; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; dynamic kinetic asymmetric transformation; diols; enzymatic transformations; catalysis; ruthenium; transfer hydrogenation; Organic chemistry; Organisk kemi; Organic Chemistry; organisk kemi;

    Sammanfattning : The major part of this thesis describes the synthesis of aliphatic secondary diols and the development of lipase- and ruthenium-catalyzed asymmetric transformations of these diols. Several acyclic 1,4-diols and 1,5-diols were synthesized, and by combining a lipase-catalyzed asymmetric transformation with a ruthenium-catalyzed epimerization, enantiomerically- and diastereomerically enriched diacetates were obtained. LÄS MER