Sökning: "Chiral discrimination"

Visar resultat 1 - 5 av 8 avhandlingar innehållade orden Chiral discrimination.

  1. 1. Interactions of chiral ions and molecules in gas phase : Towards an understanding of chiral recognition mechanism

    Författare :Oleksii Rebrov; Mats Larsson; Richard Thomas; Vitali Zhaunerchyk; Anne Zehnacker-Rentien; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; fysik; Physics;

    Sammanfattning : This thesis comprises the research related to interactions of enantiopure amino acids with chiral and achiral molecules in gas phase. The investigation of the mechanism responsible for chiral discrimination is of the special interest in this work. LÄS MER

  3. 2. Chiral recognition on cellulases : The active sites of the enzymes are involved

    Författare :Hongbin Henriksson; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Biochemistry; Biokemi; Biochemistry; Biokemi; biokemi; Biochemistry;

    Sammanfattning : Two cellobiohydrolases (CBH I and CBH II) and endoglucanase I (EG I) fromTrichoderma reesei, and CBH 58 from Phanerochaete chrysosporium were immobilized onsilica as chiral stationary phases (CSPs) in HPLC for enantioseparation of a group ofpharmaceutical compounds. CBH I and CBH 58 wore excellent chiral selectors for β-adrenergic blocking agents, whereas CBH II displayed good enantioselectivity for someother compounds The CBHs share the common feature that their active sites are located intunnels. LÄS MER

  4. 3. Enantiomeric Separations using Chiral Counter-Ions

    Författare :Jakob Haglöf; Curt Pettersson; Anders Karlsson; Jacques Crommen; Uppsala universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Capillary Electrophoresis; Chiral Counter-Ion; Divalent Dipeptide; Enantioselectivity; Electroosmosis; Chemometrics; Molecular Descriptor; Structure-Enantioselectivity Relationship; Pharmaceutical chemistry; Farmaceutisk kemi; Analytical Pharmaceutical Chemistry; Analytisk farmaceutisk kemi;

    Sammanfattning : This thesis describes the use of chiral counter-ions for the enantiomeric separation of amines in non-aqueous capillary electrophoresis. The investigations have been concentrated on studies of the influence, of the chiral counter-ion, the solvent, the electrolyte and the analyte, on the enantioselective separation. LÄS MER

  5. 4. Synthesis of Novel Polyhydroxyl Surfactants. Influence of the Relative Stereochemistry on Surfactant Properties

    Författare :Kristina Neimert-Andersson; KTH; []
    Nyckelord :Polyhydroxyl surfactants; Sugar surfactants; Stereoselective; Synthesis; Dihydroxylation; Langmuir monolayers; Chiral discrimination;

    Sammanfattning : This thesis deals with the synthesis and characterization ofnovel polyhydroxyl surfactants. The first part describes thesynthesis of a number of stereoisomers of a polyhydroxylsurfactant, and the second part concerns surface chemicalcharacterization. LÄS MER

  7. 5. Synthesis of Polyhydroxylated Surfactants : Comparison of Surfactant Stereoisomers and Investigation of Haemolytic Activity

    Författare :Kristina Neimert-Andersson; Peter Somfai; Krister Holmberg; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Polyhydroxy surfactants; Sugar surfactants; Dihydroxylation; Metathesis; Langmuir monolayers; Chiral discrimination; Haemolysis; Organic chemistry; Organisk kemi;

    Sammanfattning : I den här avhandlingen har vi studerat hur man kan göra nya tensider. En tensid är en speciell molekyl som har förmågan att lösa sig i både vatten och olja. Man kan göra följande experiment hemma: Fyll en glasburk till hälften med vatten och tillsätt en droppe matolja. LÄS MER