Sökning: "Catalytic anisotropy"

Visar resultat 1 - 5 av 7 avhandlingar innehållade orden Catalytic anisotropy.

  1. 1. Structure, Morphology, and Catalytic Properties of CuOx/CeO2 Model Catalysts

    Författare :Björn Skårman; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Synchrotron radiation; High-energy Diffraction; X-ray Absorption Fine Structure Spectroscopy.; Chemical technology and engineering; Kemiteknik och kemisk teknologi; Chemistry; Kemi; Material technology; Materiallära; materialteknik; X-ray photoelectron spectroscopy; Atomic force microscopy; Gatan Image Filter GIF ; Energy-filtered TEM; High-resolution electron microscopy; Inert gas condensation IGC ; rf Magnetron sputtering; Thermal activation; Batch reactor; Carbon monoxide oxidation; Surface sensitivity; Catalytic anisotropy; Growth; Nucleation; Topography; Roughness; Core-shell structures; Morphology; Nanostructured; Nanocomposite; Nanoparticles; Surface structure; Polycrystalline surfaces; Thin films; Copper oxide; Cerium dioxide CeO2 ; Ceria;

    Sammanfattning : Cerium dioxide, or ceria, is a chemically stable oxygen ion conducting material with a capacity to store and release oxygen, and is therefore extensively used in combustion catalysts. The Cu-Ce-O system has been identified as one of the most active catalysts for the combustion of carbon monoxide. LÄS MER

  3. 2. Optimizing Enzyme Immobilization in Mesoporous Silica - A Spectroscopic Study of the Dynamics and Spatial Distribution of the Confined Enzymes

    Författare :Pegah Sadat Nabavi Zadeh; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; fluorescence spectroscopy; dynamics; mesoporous silica; Immunogold staining; Transmission electron microscopy; anisotropy; microviscosity; real-time monitoring; Cy5.; Förster resonance energy transfer; Enzyme immobilization; Cy3;

    Sammanfattning : Enzymes as biological catalysts are immobilized in porous materials to improve the enzyme activity and simplify their purification from the reaction media in biocatalytic applications. Mesoporous silica (MPS) particles are used as a promising support material for the immobilization of enzymes. LÄS MER

  4. 3. Glypican-1: Structural and functional analysis of the N-glycosylated human protein

    Författare :Wael Awad Abdelhady; Biokemi och Strukturbiologi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Proteoglycans; glypicans; glypican-1; heparan sulphate; N-glycosylation; exostosin-proteins; X-ray crystallography; crystal dehydration; diffraction anisotropy; Small angle X-ray scattering SAXS9; protein spectroscopy;

    Sammanfattning : Glypicans are multifunctional cell surface heparan sulphate proteoglycans co-regulating numerous signalling pathways, and are thereby involved in the control of cellular division, differentiation, and morphogenesis. The heparan sulphate (HS) chains are responsible for many of those biological functions; nevertheless recent studies suggest functional roles for the glypican core proteins in mediating the signalling of various growth factors. LÄS MER

  5. 4. Structural, Electronic and Reactive Properties of Pentapyridyl - Base Metal Complexes : Relevance for Water Oxidation Catalysis

    Författare :Manuel Boniolo; Johannes Messinger; Antoni Llobet; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Water oxidation; Base metal complexes; Redox potential; Spin crossover; Magnetic anisotropy; Chemistry with specialization in Molecular Biomimetics; Kemi med inriktning mot molekylär biomimetik;

    Sammanfattning : The rationalization of chemical-physical proprieties of transition metal complexes is fundamental in order to understand and tune their reactivity. In this thesis, a systematic investigation of the geometrical and electronic properties of [M(Py5OH)Cl]+ complexes (M= Mn, Fe, Co, Ni) has been performed, and their ability to act as molecular water oxidation catalysts has been probed. LÄS MER

  7. 5. Biosensing platforms using graphene based bioreactive nanostructures with various dimensions

    Författare :Yuanyuan Han; Klaus Leifer; Jöns Hilborn; Hu Li; Boukherroub Rabah; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Graphene; nanoparticles; nanostructure; biosensors;

    Sammanfattning : Nanomaterials have brought new aspects and improvements to the biosensing field due to their unique physical and chemical properties that are not shown in the bulk state. This thesis focuses on concepting, developing and testing of biosensors where nanomaterials including graphene gold nanoparticles (AuNPs) and magnetic nanoparticles (MNPs) constitute the biosensors. LÄS MER