Sökning: "Manuel Boniolo"

Hittade 1 avhandling innehållade orden Manuel Boniolo.

1. 1. Structural, Electronic and Reactive Properties of Pentapyridyl - Base Metal Complexes : Relevance for Water Oxidation Catalysis

   Författare :Manuel Boniolo; Johannes Messinger; Antoni Llobet; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Water oxidation; Base metal complexes; Redox potential; Spin crossover; Magnetic anisotropy; Chemistry with specialization in Molecular Biomimetics; Kemi med inriktning mot molekylär biomimetik;

   Sammanfattning : The rationalization of chemical-physical proprieties of transition metal complexes is fundamental in order to understand and tune their reactivity. In this thesis, a systematic investigation of the geometrical and electronic properties of [M(Py5OH)Cl]+ complexes (M= Mn, Fe, Co, Ni) has been performed, and their ability to act as molecular water oxidation catalysts has been probed. LÄS MER