Sökning: "oxidation states"

Visar resultat 1 - 5 av 125 avhandlingar innehållade orden oxidation states.

  1. 1. Investigations on the Oxidation of Iron-chromium and Iron-vanadium Molten Alloys

    Författare :Haijuan Wang; Seshadri Seetharaman; Ashok Lahiri; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Oxidation; High-alloy steelmaking; Retention; CO2-O2; Fe-Cr melt; Fe-Cr-C melt; Fe-V melt; Vanadium containing slags; Kinetics; Thermodynamics properties.; Metallurgical process engineering; Metallurgisk processteknik; Materials science; Teknisk materialvetenskap;

    Sammanfattning : With the progress of high alloy steelmaking processes, it is essential to minimize the loss of valuable metals, like chromium and vanadium during the decarburization process, from both economic as well as environmental view points. One unique technique to realize this aim, used in the present work, is the decarburization of high alloy steel grades using oxygen with CO2 in order to reduce the partial pressure of oxygen. LÄS MER

  2. 2. The Effects of Morphology and Surface Oxidation of Stainless Steel Powder in Laser Based-Powder Bed Fusion

    Författare :Dmitri Riabov; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; additive manufacturing; powder surface; 316L stainless steel; oxides; oxidation; laser based-powder bed fusion; morphology; powder properties; powder production;

    Sammanfattning : Laser based-powder bed fusion (LB-PBF) is one of the many techniques within additive manufacturing (AM) that allows for near net shape manufacturing of metallic components. By using powder feedstock, it is possible to spread thin layers of powder and further selectively fuse powder in a repetitive manner until the component is completed. LÄS MER

  3. 3. The Use of Aliquat-336 in a Partitioning and Transmutation Process and a Kinetic Study of the Oxidation of U(IV) to U(VI)

    Författare :Anders Landgren; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; partitioning; quaternary ammonium salts; transmutation; hydrolysis; Aliquat-336; liquid-liquid extraction; kinetics; oxidation; uranium IV ;

    Sammanfattning : Spent nuclear fuel contains several long-lived radionuclides that must be stored in a safe manner for a long time. Transmutation of these radionuclides into short-lived or stable nuclides reduces the necessary storage time by several orders of magnitude. The nuclides most suitable for transmutation are those of the actinides. LÄS MER

  4. 4. Molecular Approaches to Photochemical Solar Energy Conversion : Towards Synthetic Catalysts for Water Oxidation and Proton Reduction

    Författare :Gerriet Eilers; Reiner Lomoth; Leif Hammarström; Wolfgang Lubitz; Uppsala universitet; []
    Nyckelord :Physical chemistry; artificial photosynthesis; solar fuel; WOC; OEC; accumulative electron transfer; hydrogenase mimic; oxygen evolution; proton reduction; water oxidation; Fysikalisk kemi;

    Sammanfattning : A molecular system capable of photoinduced water splitting is an attractive approach to solar energy conversion. This thesis deals with the functional characterization of molecular building blocks for the three principal functions of such a molecular system: Photoinduced accumulative charge separation, catalytic water oxidation, and catalytic proton reduction. LÄS MER

  5. 5. Spectroscopic characterisation of surface hydroxyls during catalytic methane oxidation

    Författare :Peter Velin; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; XAS; Water inhibition; Supported palladium; Sustainable transports; Methane oxidation; Operando spectroscopy; DRIFTS; Environmental catalysis;

    Sammanfattning : Implementation of methane rich fuels as to develop sustainable vehicle transports requires improved catalytic exhaust aftertreatment technologies to convert engine-out methane emissions to carbon dioxide and water by total oxidation. A main challenge is that water formed during combustion inhibits the methane oxidation reaction even over the most active palladium-based catalysts presently known. LÄS MER