Sökning: "absolute asymmetric synthesis"

Visar resultat 6 - 9 av 9 avhandlingar innehållade orden absolute asymmetric synthesis.

1. 6. Breaking the symmetry: creation and transfer of optical activity via total spontaneous resolution and stereoselective reactions

   Författare :Susanne Olsson; Göteborgs universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; absolute asymmetric synthesis; enantioselective reactions; chirality; spontaneous resolution; conglomerate; organometallic chemistry; coordination compounds; attritionenhanced deracemisation; polymorphism; organolithium compounds; single-crystal X-ray crystallography;

   Sammanfattning : The generation of optical activity from achiral or racemic precursors – absolute asymmetric synthesis – is discussed in relation to the origin of biomolecular homochirality but is also often (incorrectly) regarded as being impossible. One approach to absolute asymmetric synthesis is the use of compounds that form chiral crystals. LÄS MER

3. 7. Dynamic Chemistry for Asymmetric Synthesis, Molecular Motion and Constitutional Exchange

   Författare :Yansong REN; Licheng Sun; Olof Ramström; Anna Hirsch; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; dynamic chemistry; constitutional dynamic chemistry; motional dynamics; dynamic kinetic resolution; enzyme; subtilisin Carlsberg; Candida antarctica lipase B; anti-HIV; 1; 3-oxathiolane; dynamic exchange; enamines; E Z-isomerization; molecular switches; aggregation; gelation; fluorescence.; dynamisk kemi; konstitutionell dynamisk kemi; molekylär rörelsedynamik; dynamisk kinetisk resolvering; enzym; subtilisin Carlsberg; Candida antarctica lipase B; anti-HIV; 1; 3-oxatiolan; dynamisk utbyte; enaminer; E Z-isomerisering; molekylära omkopplare; aggregering; gelbildning; fluorescens.; Kemi; Chemistry;

   Sammanfattning : Living matter is built on complex dynamic systems consisting of numerus biotransformations. By exploiting the adaptive and evolutive behaviors ofmolecular matter, dynamic chemistry has developed as an important tool tounderstand the organization of nonliving matter into complex living systems. LÄS MER

4. 8. Creating Optical Activity: Total Spontaneous Resolution and Viedma Ripening

   Författare :Per Martin Björemark; Göteborgs universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Optical activity; absolute asymmetric synthesis; total spontaneous resolution; Viedma ripening; grinding; chirality; conglomerate; coordination compound; coordination polymer; single crystal X-ray diffraction; solvent free oxidation; nantioselective sulfide oxidation; solid state VCD;

   Sammanfattning : The creation of optical activity has been considered as something impossible even though reports of such creation via total spontaneous resolution since the 1940´s have been published. More recently Viedma ripening have been developed that also produce enantiopure bulk product. Both methods are examples of absolute asymmetric synthesis i.e. LÄS MER

5. 9. Asymmetric hydrogenation of allylic alcoholsusing iridium catalysts

   Författare :Jianguo Liu; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; organisk kemi; Organic Chemistry;

   Sammanfattning : The first part of this thesis is focussed on the enantioselective iridium catalyzeda symmetric hydrogenation of allylic alcohols. The study involved the preparation of a range of allylic alcohols. LÄS MER