Sökning: "total spontaneous resolution"
Visar resultat 1 - 5 av 8 avhandlingar innehållade orden total spontaneous resolution.
1. Creating Optical Activity: Total Spontaneous Resolution and Viedma Ripening
Sammanfattning : The creation of optical activity has been considered as something impossible even though reports of such creation via total spontaneous resolution since the 1940´s have been published. More recently Viedma ripening have been developed that also produce enantiopure bulk product. Both methods are examples of absolute asymmetric synthesis i.e. LÄS MER
2. Breaking the symmetry: creation and transfer of optical activity via total spontaneous resolution and stereoselective reactions
Sammanfattning : The generation of optical activity from achiral or racemic precursors – absolute asymmetric synthesis – is discussed in relation to the origin of biomolecular homochirality but is also often (incorrectly) regarded as being impossible. One approach to absolute asymmetric synthesis is the use of compounds that form chiral crystals. LÄS MER
3. Absolute Asymmetric Synthesis
Sammanfattning : Absolute asymmetric synthesis is the synthesis of optically active products from achiral or racemic precursors only. This has generally been regarded as impossible and is relevant in the discussion of the origins of biomolecular homochirality. LÄS MER
4. Synthesis, Structure, Total Spontaneous Resolution, and Solid-State Reactions of Chiral Metal Complexes
Sammanfattning : .... LÄS MER
5. Homochiral crystals for selective synthesis
Sammanfattning : Six new coordination compounds were prepared from monodentate sulfide ligands and copper(I) halides and their crystal structures were determined by single-crystal X-ray diffraction. The aim was to prepare coordination polymers that crystallize as conglomerates in order to use them in total spontaneous resolution. LÄS MER