Sökning: "organolithium compounds"

Hittade 1 avhandling innehållade orden organolithium compounds.

1. 1. Breaking the symmetry: creation and transfer of optical activity via total spontaneous resolution and stereoselective reactions

   Författare :Susanne Olsson; Göteborgs universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; absolute asymmetric synthesis; enantioselective reactions; chirality; spontaneous resolution; conglomerate; organometallic chemistry; coordination compounds; attritionenhanced deracemisation; polymorphism; organolithium compounds; single-crystal X-ray crystallography;

   Sammanfattning : The generation of optical activity from achiral or racemic precursors – absolute asymmetric synthesis – is discussed in relation to the origin of biomolecular homochirality but is also often (incorrectly) regarded as being impossible. One approach to absolute asymmetric synthesis is the use of compounds that form chiral crystals. LÄS MER