Sökning: "Organic phosphorus"

Visar resultat 16 - 20 av 133 avhandlingar innehållade orden Organic phosphorus.

1. 16. Molecular Motion in Frustrated Lewis Pair Chemistry: insights from modelling

   Författare :Maoping Pu; Timofei Privalov; Todd Martinez; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; CO2 capture; hydrogen activation; molecular motion; ab initio molecular dynamics; frustrated Lewis pair; quantum chemical modelling; reaction mechanism; Organic Chemistry; organisk kemi;

   Sammanfattning : Mechanisms of reactions of the frustrated Lewis pairs (FLPs) with carbon dioxide (CO2) and hydrogen (H2) are studied by using quantum chemical modelling. FLPs are relatively novel chemical systems in which steric effects prevent a Lewis base (LB) from donating its electron pair to a Lewis acid (LA). LÄS MER

3. 17. Flexibility – a tool for chirality control in asymmetric catalysis

   Författare :Raivis Zalubovskis; Christina Moberg; Alexandre Alexakis; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; flexibility; symmetry; dissymmetry; asymmetric catalysis; chiral ligands; pseudo-C2; pseudo-CS; conformational study; rotation barrier; pyrrolidines; phospholanes; azepines; phosphepines; supramolecular; hydrogenation; allylic alkylation; silaboration; palladium; rhodium; nickel; platinum; iridium.; Organic chemistry; Organisk kemi;

   Sammanfattning : This thesis deals with the design and synthesis of ligands for asymmetric catalysis: palladium catalyzed allylic alkylations, and rho-dium and iridium catalyzed hydrogenations of olefins. Chirally flexible phosphepine ligands based on biphenyl were synthesized and their properties were studied. LÄS MER

4. 18. Studies of ash transformation processes in thermochemical co-conversion of phosphorus-rich manure and sludge with biomass residues

   Författare :Gustav Häggström; Marcus Öhman; Anders Lagerkvist; Nils Skoglund; Flemming Jappe Frandsen; Luleå tekniska universitet; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; sewage sludge; agricultural residues; forest residues; ash transformation; potassium; phosphorus; combustion; gasification; phosphorus recovery; Energy Engineering; Energiteknik;

   Sammanfattning : Efficient use of resources and sustainable recovery of various materials are important to minimize the anthropogenic impact on the climate and environment. One such resource is the phosphorus (P) present in manure and sewage sludge. LÄS MER

5. 19. Phosphorus recovery from sewage sludge fluidized bed gasification processes

   Författare :Thomas Karl Hannl; Marcus Öhman; Matthias Kuba; Nils Skoglund; Flemming Jappe Frandsen; Luleå tekniska universitet; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; gasification; sewage sludge; agricultural residues; bed material; fluidized bed; feldspar; ash transformation; potassium; phosphorus; ICP-AES MS; SEM; EDS; XRD; thermodynamic equilibrium modeling; Energy Engineering; Energiteknik;

   Sammanfattning : One of the most sustainable pathways of sewage sludge treatment in recent years has been thermal conversion. The benefits of thermal treatment of sewage sludge are the recovery of energy or valuable chemical products, the destruction of harmful organic compounds, the separation of heavy metals from the P-rich coarse ash fraction, and the decreased and sanitized ash volume. LÄS MER

7. 20. Treatment of domestic wastewater using microbiological processes and hydroponics in Sweden

   Författare :Anna Norström; Gunnel Dalhammar; Jörgen Hanaeus; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Microbiology; biological; hydroponics; microbial composition; nitrogen; organic matter; phosphorus; small scale; theoretical energy requirements; wastewater treatment.; Mikrobiologi; Microbiology; Mikrobiologi;

   Sammanfattning : Conventional end-of-pipe solutions for wastewater treatment have been criticized from a sustainable view-point, in particular regarding recycling of nutrients. The integration of hydroponic cultivation into a wastewater treatment system has been proposed as an ecological alternative, where nutrients can be removed from the wastewater through plant uptake; however, cultivation of plants in a temperate climate, such as Sweden, implies that additional energy is needed during the colder and darker period. LÄS MER