Sökning: "Organic phosphorus"

Visar resultat 6 - 10 av 133 avhandlingar innehållade orden Organic phosphorus.

  1. 6. Organic Phosphorus Compounds in Aquatic Sediments : Towards Molecular Identification with Mass Spectrometry

    Författare :Heidi De Brabandere; Monica Waldebäck; Emil Rydin; Per J. R. Sjöberg; Rolf Danielsson; William T. Cooper; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; electrospray ionisation; mass spectrometry; liquid chromatography; organic phosphorus; aquatic sediment; eutrophication; sample preparation; extraction; Analytical chemistry; Analytisk kemi;

    Sammanfattning : Phosphorus (P) regulates trophic status in most aquatic systems. However, only bioavailable P contributes to primary production. In most lakes and shallow seas, mineralisation of sediment P into its bioavailable form and its release to the water column is important for maintaining primary production. LÄS MER

  3. 7. Synthesis of C(sp2)-P bonds by palladium-catalyzed reactions : Mechanistic investigations and synthetic studies

    Författare :Marcin Kalek; Jacek Stawinski; Jean-Luc Montchamp; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Organisk kemi; Organic Chemistry; organisk kemi;

    Sammanfattning : This thesis focuses on synthetic and mechanistic aspects of palladium-catalyzed C(sp2)-P bond-forming reactions, with the aim to develop mild and efficient methods for the synthesis of biologically active phosphorus compounds, e.g. DNA analogs. LÄS MER

  4. 8. Studies on nucleoside H-phosphonoselenoate chemistry and chalcogen exchange reaction between P(V) and P(III) compounds

    Författare :Martin Kullberg; Jacek Stawinski; Wojciech Markiewicz; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Phosphorus chemistry; H-phosphonate; H-phosphonoselenoate; nucleotide analogues; selenization; selenium transfer; phosphoroselenoate; Organic chemistry; Organisk kemi;

    Sammanfattning : In this thesis, the chemistry of compounds containing P-Se bonds has been studied. As a new addition to this class of compounds, H-phosphonoselenoate monoesters, have been introduced and two synthetic pathways for their preparation have been developed. LÄS MER

  5. 9. Analysis and speciation of organic phosphorus in environmental matrices : Development of methods to improve 31P NMR analysis

    Författare :Johan Vestergren; Gröbner Gerhard; Jurgen Schleucher; Ulrik Ilstedt; Per Persson; Reiner Giesler; Benjamin L. Turner; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Phosphorus; soil; 31P NMR; NaOH EDTA; terrestrial; sulfide; speciation; bioavailability; paramagnetic; humus; boreal; tropical; multi-dimensional; agroforestry; chronosequence; fysikalisk kemi; Physical Chemistry;

    Sammanfattning : Phosphorus (P) is an essential element for life on our planet. It is central in numerous biochemical processes in terrestrial and aqueous ecosystems including food production; and it is the primary growth-limiting nutrient in some of the world’s biomes. LÄS MER

  7. 10. Novel Organophosphorus Compounds for Materials and Organic Synthesis

    Författare :Keyhan Esfandiarfard; Sascha Ott; Declan Gilheany; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : This thesis is devoted to the development of new organophosphorus compounds for potential uses in material science and as reagents in Organic Chemistry. Organophosphorus compounds in a single molecule or organic electronics context are appealing as the phosphorous centers perturb the electronic properties of the π-conjugated systems while at the same time provide synthetic handles for subsequent synthetic modifications. LÄS MER