Sökning: "hydride transfer"
Visar resultat 11 - 15 av 29 avhandlingar innehållade orden hydride transfer.
11. New Methods for the Synthesis of Vicinal Stereocenters : Palladium-Catalyzed Domino Reactions and Asymmetric Transfer Hydrogenation
Sammanfattning : In this thesis the synthesis of vicinal stereocenters is investigated in two distinct contexts, namely the construction of 3,3-disubstituted oxindoles and the synthesis of b-hydroxy-a-amino acids. Both scaffolds are prevalent in a range of natural products and biologically relevant compounds and, therefore, methods for their synthesis are of great import. LÄS MER
12. Transient electrochemical methods for investigation of porous battery electrodes
Sammanfattning : This thesis treats electrochemical methods used to studybattery materials. Two different types of materials are used asmodel systems in this study, metal hydride alloys used in thenickel-metal hydride battery and LiMn2O4suggested for use in the lithium-ion battery. Thetwo model systems are used to critically analyse differentexperimental methods. LÄS MER
13. Theoretical Studies on Artificial Water Splitting-Water Oxidation and Proton Transfer
Sammanfattning : The present thesis is concerned with the theoretical studies on artificial water splitting process. As the quick development of research on utilizing of solar energy, which is a green, clean, and renewable energy source, many research groups focus their attention on artificial photo-synthesis systems inspired by the photosystem I and II. LÄS MER
14. Molecular Approaches to Photochemical Solar Energy Conversion : Towards Synthetic Catalysts for Water Oxidation and Proton Reduction
Sammanfattning : A molecular system capable of photoinduced water splitting is an attractive approach to solar energy conversion. This thesis deals with the functional characterization of molecular building blocks for the three principal functions of such a molecular system: Photoinduced accumulative charge separation, catalytic water oxidation, and catalytic proton reduction. LÄS MER
15. Potential surfaces for chemical reactions investigated by accurate quantum chemical methods
Sammanfattning : The main object of the thesis is the investigation of mechanisms for some inorganic and metallo-organic reactions by means of accurate multiconfigurational SCF and configuration interaction calculations. Stepwise dissociation of diimide into N2+H2 is found to be slightly preferred before a concerted mechanism. LÄS MER
