Avancerad sökning

Hittade 3 avhandlingar som matchar ovanstående sökkriterier.

1. 1. Synthesis of aromatic bis- and tris(amino acids) and chiral dendrimers

   Författare :Andreas Ritzén; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organic chemistry; HWE reaction; asymmetric hydrogenation; Heck reaction; Amino acids; chiral dendrimers;

   Sammanfattning : A number of protected aromatic bis- and tris(amino acids) have been synthesised by catalytic asymmetric hydrogenation of the corresponding didehydroamino acid derivatives. The didehydroamino acid derivatives were prepared either by a Heck coupling of a 2-amidoacrylate with an aryl dihalide, or by Horner-Wadsworth-Emmons olefination of aromatic aldehydes with phosphonylglycine reagents. LÄS MER

3. 2. Asymmetric Catalysis : Ligand Design and Conformational Studies

   Författare :Kristina Hallman; KTH; []
   Nyckelord :asymmetric catalysis; chiral ligand; oxazolines; conformational study; allylic substitution; polymer-bound ligands; dendritic ligands; crown ether; oxidations; palladacycle;

   Sammanfattning : This thesis deals with the design of ligands for efficientasymmetric catalysis and studies of the conformation of theligands in the catalytically active complexes. All ligandsdeveloped contain chiral oxazoline heterocycles. LÄS MER

4. 3. Synthesis and characterization of dendritic macromolecules based on 2,2-bis(hydroxymethyl)propionic acid

   Författare :Henrik Ihre; KTH; []
   Nyckelord :;

   Sammanfattning : Dendrimers are a relatively new type of macromolecules characterized by a well-defined, highly branthed, layered structure with a multitude of chain ends, adopting a globular shape at higher molar masses. Dendrimers are usually constructed from ABx type of monomers in either one of the two step-wise approaches known as thedivergentor theconvergent growth approach. LÄS MER