Sökning: "Heterogeneous reactions"

Visar resultat 21 - 25 av 146 avhandlingar innehållade orden Heterogeneous reactions.

  1. 21. Thermal and Photon Stimulated Reactions on Metal Particles

    Författare :Kristina Wettergren; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Plasmons; Platinum Clusters; Platinum Nanoparticles; Hydrogen Oxidation; Sodium; Silver Nanoparticles; Nitric Oxide; Photodesorption; Sintering; Graphite; Water;

    Sammanfattning : The interaction between molecules and solid surfaces influence our daily lives in many ways. One important example is heterogeneous catalysis where surface reactions, for example, are used for production of chemicals and exhaust after-treatment. LÄS MER

  2. 22. Ultrafast Probing of CO Reactions on Metal Surfaces : Changes in the molecular orbitals during the catalysis process

    Författare :Jörgen Gladh; Henrik Öström; Nils Mårtensson; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Hetrogenous catalysis; CO; transition metals; Ultrafast probing; oxidation; desorption; dissociation; kemisk fysik; Chemical Physics;

    Sammanfattning : This thesis presents experimental studies of three different chemical reaction steps relevant for heterogeneous catalysis: dissociation, desorption, and oxidation. CO on single-crystal metal surfaces was chosen as the model systems. LÄS MER

  3. 23. Homogeneous and heterogeneous Cp*Ir(III) catalytic systems : Mechanistic studies of redox processes catalyzed by bifunctional iridium complexes, and synthesis of iridium-functionalized MOFs

    Författare :Greco González Miera; Belén Martín-Matute; Matt Clarke; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; catalysis; bifunctional; metal-ligand cooperation; amine alkylation; Hammett; kinetics; acceptorless alcohol dehydrogenation; MOF; transition metal; synchrotron; organisk kemi; Organic Chemistry;

    Sammanfattning : The purpose of this doctoral thesis is to investigate and develop catalytic processes mediated by iridium(III) complexes. By understanding the mechanisms, the weaknesses of the designed catalysts can be identified and be overcome in the following generation. LÄS MER

  4. 24. Surface and Interface Phenomena Studied with Pd Metal-Oxide-semiconductor Structures : Adsorption, catalytic reactions, hydrogen sensing and Pd restructuring

    Författare :Mats Eriksson; Wolfgang Göpel; Linköpings universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : The electronic properties of palladium metal-oxide-semiconductor (Pd-MOS) structures are highly sensitive to hydrogen over a large pressure range. Such devices have been found useful in several applications, e.g. as a chemical sensing element in the so called electronic nose. LÄS MER

  5. 25. Mechanistic investigation of platinum and palladium catalysed cross- coupling reactions. Implications for the Stille and Heck reactions

    Författare :Patrik Nilsson; Kemiska institutionen; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Metallorganisk kemi; Organometallic chemistry; Oorganisk kemi; Inorganic chemistry; parameter fitting; numerical solutions; platinum II ; palladium II ; NMR spectroscopy; transmetallation; Heck; Stille; kinetics; mechanism;

    Sammanfattning : The present thesis deals with various types of palladium(II) and platinum(II) complexes and their use in homogeneous catalysis. The focus has been devoted to mechanistic investigations concerning the Stille and Heck reactions and studies under both catalytic and stoichiometric conditions were conducted. LÄS MER