Sökning: "Heterogeneous reactions"
Visar resultat 21 - 25 av 146 avhandlingar innehållade orden Heterogeneous reactions.
21. Thermal and Photon Stimulated Reactions on Metal Particles
Sammanfattning : The interaction between molecules and solid surfaces influence our daily lives in many ways. One important example is heterogeneous catalysis where surface reactions, for example, are used for production of chemicals and exhaust after-treatment. LÄS MER
22. Ultrafast Probing of CO Reactions on Metal Surfaces : Changes in the molecular orbitals during the catalysis process
Sammanfattning : This thesis presents experimental studies of three different chemical reaction steps relevant for heterogeneous catalysis: dissociation, desorption, and oxidation. CO on single-crystal metal surfaces was chosen as the model systems. LÄS MER
23. Homogeneous and heterogeneous Cp*Ir(III) catalytic systems : Mechanistic studies of redox processes catalyzed by bifunctional iridium complexes, and synthesis of iridium-functionalized MOFs
Sammanfattning : The purpose of this doctoral thesis is to investigate and develop catalytic processes mediated by iridium(III) complexes. By understanding the mechanisms, the weaknesses of the designed catalysts can be identified and be overcome in the following generation. LÄS MER
24. Surface and Interface Phenomena Studied with Pd Metal-Oxide-semiconductor Structures : Adsorption, catalytic reactions, hydrogen sensing and Pd restructuring
Sammanfattning : The electronic properties of palladium metal-oxide-semiconductor (Pd-MOS) structures are highly sensitive to hydrogen over a large pressure range. Such devices have been found useful in several applications, e.g. as a chemical sensing element in the so called electronic nose. LÄS MER
25. Mechanistic investigation of platinum and palladium catalysed cross- coupling reactions. Implications for the Stille and Heck reactions
Sammanfattning : The present thesis deals with various types of palladium(II) and platinum(II) complexes and their use in homogeneous catalysis. The focus has been devoted to mechanistic investigations concerning the Stille and Heck reactions and studies under both catalytic and stoichiometric conditions were conducted. LÄS MER