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Visar resultat 1 - 5 av 146 avhandlingar som matchar ovanstående sökkriterier.

  1. 1. Particle-fluid interactions under heterogeneous reactions

    Författare :Thamali Rajika Jayawickrama; Kentaro Umeki; Henrik Ström; Luleå tekniska universitet; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Stefan flow; drag coefficient; particle-laden flow; reacting flow; Energiteknik; Energy Engineering;

    Sammanfattning : Particle-laden flows involve in many energy and industrial processes within a wide scale range. Solid fuel combustion and gasication, drying and catalytic cracking are some of the examples. It is vital to have a better understanding of the phenomena inside the reactors involving in particle-laden flows for process improvements and design. LÄS MER

  3. 2. Particle-fluid interactions under heterogeneous reactions

    Författare :Thamali Rajika Jayawickrama; Kentaro Umeki; Nils Erland L. Haugen; Matthaus Babler; Muhammad Aqib Chishty; Henrik Ström; Luleå tekniska universitet; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Stefan flow; drag coefficient; Nusselt number; Sherwood number; particle-fluid flow; reacting flow; Energy Engineering; Energiteknik;

    Sammanfattning : Particle-fluid flows are involved in many natural processes and industrial applications; some examples are drying, solid fuel combustion, gasification, and catalytic cracking. It is vital to understand the phenomena involved in particle-fluid flows in depth for design, predictions and process improvements. LÄS MER

  4. 3. Transition Metal-Catalyzed Redox Reactions : A Journey from Homogeneous Ruthenium to Heterogeneous Palladium Catalysis

    Författare :Oscar Verho; Jan-Erling Bäckvall; Manfred Reetz; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; organisk kemi; Organic Chemistry;

    Sammanfattning : The first part of the thesis covers the development and utilization of electronically modified (pentaarylcyclopentadienyl)Ru-complexes in the racemization of secondary alcohols. This study revealed that the electronic properties of the substrate were the main factors dictating whether β-hydride elimination or hydride re-addition becomes the rate-determining step of the racemization process. LÄS MER

  5. 4. Catalytic reactions with palladium supported on mesocellular foam : Applications in hydrogenation, isomerization, and C-C bond forming reactions

    Författare :Anuja Nagendiran; Jan-Erling Bäckvall; Shu Kobayashi; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Mesocellular foam; Heterogeneous palladium catalysis; nanopalladium; organisk kemi; Organic Chemistry;

    Sammanfattning : The major part of this thesis concerns the development of catalytic methodologies based on palladium nanoparticles immobilized on aminopropyl-functionalized siliceous mesocellular foam (Pd0-AmP-MCF). The catalytic activity of the precursor to the nanocatalyst, PdII-AmP-MCF is also covered by this work. LÄS MER

  7. 5. Surface reactions and chemical bonding in heterogeneous catalysis

    Författare :Henrik Öberg; Lars G. M. Pettersson; Philippe Sautet; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; kemisk fysik; Chemical Physics;

    Sammanfattning : This thesis summarizes studies which focus on addressing, using both theoretical and experimental methods, fundamental questions about surface phenomena, such as chemical reactions and bonding, related to processes in heterogeneous catalysis. The main focus is on the theoretical approach and this aspect of the results. LÄS MER