Sökning: "C-F bond activation"

Hittade 1 avhandling innehållade orden C-F bond activation.

  1. 1. Lanthanide-mediated C-F Bond Activation Method Development and Mechanistic Investigation

    Författare :Mario Janjetovic; Göteborgs universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; C-F bond activation; fluorine chemistry; lanthanides; single-electron transfer reagent; Lewis acid; chemoselectivity; synthetic method; catalysis;

    Sammanfattning : The use of transition-metals and main-group Lewis acids has proven to be an outstanding source for activation and subsequent functionalization of fluorinated compounds. However, the first is mainly limited to C(sp2)–F bonds which partially are activated by an adjacent heteroatom, and the latter is limited to simple C(sp3)–F bonds due to particularly strong Lewis acid character. LÄS MER