Sökning: "Star-shaped architecture"

Hittade 3 avhandlingar innehållade orden Star-shaped architecture.

  1. 1. Macromolecular design and architecture of aliphatic polyesters

    Författare :Karin Odelius; Ann-Christine Albertsson; Helmut Keul; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Ring-opening polymerization; L-lactide; 1; 5-dioxepane-2-one; ε-caprolactone; Polymerization kinetics; Star-shaped architecture; Spirocyclic tin initiator; Polymer chemistry; Polymerkemi;

    Sammanfattning : Public health care has reached a level where tissue or organ reconstruction by means of biodegradable short-term implants via e.g. tissue engineering will be practicable in the near future. LÄS MER

  3. 2. Novel Possibilities for Advanced Molecular Structure Design for Polymers and Networks

    Författare :Anna Finne; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; ring-opening polymerization; coordination-insertion; germanium; cyclic tin alkoxides; spirocyclic initiators; poly L-lactide ; poly 1; 5-dioxepan-2-one ; triblock; star-shaped; network; functionalization; morphology; AFM; Polymer chemistry; Polymerkemi;

    Sammanfattning : Synthetic and degradable polymers are an attractive choicein many areas, since it is possible to control the way in whichthey are manufactured; more specifically, pathways tomanipulate the architecture, the mechanical properties and thedegradation times have been identified. In this work,L-lactide, 1,5-dioxepan-2-one and ε-caprolactone were usedas monomers to synthesize polymers with different architecturesby ring-opening polymerization. LÄS MER

  4. 3. degradable electroactive polymers: Synthesis, Macromolecular architecture and scaffold design

    Författare :Baolin Guo; Ann-Christine Albertsson; Patric Jannasch; KTH; []
    Nyckelord :Poly lactide ; poly ε-caprolactone ; ring-opening polymerization; carboxyl-capped aniline trimer; carboxyl-capped aniline pentamer; phenyl amino-capped aniline tetramer; coupling reaction; DCC DMAP system; degradability; electroactivity; conductivity; macromolecular architecture; chitosan; hydrogel; block copolymer; functionalization; oxidative coupling reaction; self-assembly; toxicity; tubular porous scaffold; neural tissue engineering.;

    Sammanfattning : Electrically conducting polymers induce specific cellular responses at the molecular level. One of the crucial limitations of the use of conducting polymers in tissue engineering is their inability to degrade. LÄS MER