Sökning: "Organisk"

Visar resultat 16 - 20 av 1077 avhandlingar innehållade ordet Organisk.

  1. 16. [11C]Carbon Monoxide in Palladium- / Selenium-Promoted Carbonylation Reactions : Synthesis of 11C-Imides, Hydrazides, Amides, Carboxylic Acids, Carboxylic Esters, Carbothioates, Ketones and Carbamoyl Compounds

    Författare :Farhad Karimi; Kalman Szabo; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Organisk kemi; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

    Sammanfattning : [11C]Carbon monoxide in low concentrations has been used in palladium- or seleniummediated carbonylation reactions such as the synthesis of 11C-imides, hydrazides, amides, carboxylic acids, esters, carbothioates, ketones and carbamoyl compounds.In these reactions aryl iodides have been used in most cases. LÄS MER

  2. 17. Catalysts for Oxygen Production and Utilization : Closing the Oxygen Cycle: From Biomimetic Oxidation to Artificial Photosynthesis

    Författare :Erik Karlsson; Jan-Erling Bäckvall; Björn Åkermark; Jerker Mårtensson; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; oxygen; catalytic oxidation; biomimetic oxidation; artificial photosynthesis; water oxidation; DFT calculations; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis describes the development and study of catalysts for redox reactions, which either utilize oxygen or hydrogen peroxide for the purpose of selectively oxidizing organic substrates, or produce oxygen as the necessary byproduct in the production of hydrogen by artificial photosynthesis.The first chapter gives a general introduction about the use of environmentally friendly oxidants in the field of organic synthesis, and about the field of artificial photosynthesis. LÄS MER

  3. 18. Development of methods for stereospecific synthesis of α- and β-D-fructofuranosides and β-D-glucuronic acid pyranosides and application of these methods in the assembly of bacterial polysaccharide structures

    Författare :Christian Krog-Jensen; Michael Bols; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Organisk kemi; Organic Chemistry; organisk kemi;

    Sammanfattning : .... LÄS MER

  4. 19. Transition metal- and lipase-catalyzed reactions : Dynamic resolutions, hydrogen transfer and enzyme engineering

    Författare :Patrik Krumlinde; Jan-Erling Bäckvall; Johannes G. de Vries; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Dynamic kinetic resolution; dynamic kinetic asymmetric transformation; hydrogen transfer; directed evolution; enzyme engineering; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis mainly focuses on chemoenzymatic processes and can be divided into three parts: The first part of the thesis, chapters 2-4, is devoted to the development of combined ruthenium- and enzyme-catalyzed dynamic processes. In these processes the metal catalyst racemizes (epimerizes) the alcohol substrate via hydrogen transfer and the enzyme transforms the substrate into enantiomerically enriched product. LÄS MER

  5. 20. Expanding the H-phosphonate and H-phosphonothioate chemistry towards biologically important phosphate analogs

    Författare :Gaston Lavén; Jacek Stawinski; Wojciech T. Markiewicz; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Phosphonate; phosphonothioate; H-phosphonate; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis focuses on chemical transformations of H-phosphonate and H-phosphonothioate and can be divided in two parts. The first part, is devoted to the development of the palladium-catalyzed P-C bond formation. Both mechanistic and synthetic studies of the transformations have been performed. LÄS MER