Sökning: "Heterogeneous palladium catalysis"

Visar resultat 1 - 5 av 33 avhandlingar innehållade orden Heterogeneous palladium catalysis.

  1. 1. Palladium-catalyzed lignin valorization : Towards a lignin-based biorefinery

    Författare :Maxim Galkin; Joseph Samec; Rafael Luque; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; Lignin; Heterogeneous Catalysis; Palladium; Biomass; Depolymerization; Reduction; Oxidation; Biorefinery; Transfer Hydrogenolysis; Organic Chemistry; Organisk kemi;

    Sammanfattning : The work described in this thesis focuses on the cleavage of the β-O-4′ bond, which is the most abundant interunit linkage in the lignin polymer.In the first part, three methods based on palladium catalysis have been developed and their applicability has been verified using lignin model compounds. LÄS MER

  2. 2. Coke on Supported Palladium and Platinum Catalysts

    Författare :Mikael Larsson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; TPO; palladium; deactivation; coke; propane dehydrogenation; microbalance; vegetable oil hydrogenation; acetylene hydrogenation; catalysis; platinum;

    Sammanfattning : Catalyst deactivation by coke formation has been investigated in three heterogeneous catalytic processes, propane dehydrogenation, acetylene hydrogenation and hydrogenation of vegetable oil. Palladium and/or platinum supported on alumina were used as catalysts in all reactions. LÄS MER

  3. 3. Alloy Plasmonics - Fundamentals and Application in Catalysis

    Författare :Christopher Tiburski; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; CO oxidation; nanoparticles; gold; heterogeneous catalysis; LSPR; nanoalloys; nanofabrication; light; dielectric function; palladium;

    Sammanfattning : Alloys have for a long time been important in the development of our society; from the bronze age, where man learned how to alloy copper with tin, to today, where many products are made of steel and aluminum alloys. Similarly, but maybe not as generally well known, also in heterogeneous catalysis alloys are explored to develop solutions to increase activity and selectivity of chemical processes. LÄS MER

  4. 4. Development and Applications of Surface-Confined Transition Metal Complexes : Heterogeneous Catalysis and Anisotropic Particle Surfaces

    Författare :Kristofer Eriksson; Jan-Erling Bäckvall; Graham Hutchings; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; heterogeneous catalysis; anisotropic particles; protein gradients; nanoparticles; organisk kemi; Organic Chemistry;

    Sammanfattning : The main focus of this thesis has been directed towards developing novel surface-confined transition metal complexes for applications in heterogeneous catalysis and for the preparation of anisotropic particle surfaces. The first part describes the heterogenization of a homogeneous transition metal-based catalyst tetraphenyl cobalt porphyrin (CoTPP) on silicon wafers and on silica particles. LÄS MER

  5. 5. Catalytic and Electrocatalytic Transformations with Palladium and Nickel : Scope and mechanistic investigations

    Författare :Alejandro Valiente Sánchez; Belén Martín-Matute; King Kuok (Mimi) Hii; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic Chemistry; Heterogeneous Catalysis; Metal-organic frameworks; Nickel; Palladium; Electrocatalysis; Cross-coupling; Hydrogenation; organisk kemi; Organic Chemistry;

    Sammanfattning : The work presented in this thesis is based on methodology development and mechanistic investigations using heterogeneous palladium and nickel catalysts. Following the introduction (Chapter 1), Chapter 2 presents a summary of the synthesis and characterization of the MOF-supported Pd catalysts (Pd @ MOF) that are used in this thesis. LÄS MER