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Visar resultat 1 - 5 av 12 avhandlingar som matchar ovanstående sökkriterier.

  1. 1. Efficiency and Selectivity in the Chlorate Process

    Författare :Aleksandra Lindberg; Ann Cornell; Susanne Holmin; Eva Blomberg; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; electrolysis; chlorate process; anodes; cathodes; selectivity; chromate; chromium VI ; DSA; HER; OER; ClER; oxygen; chlorate; hypochlorite; electrocatalysis; catalysis; Chemical Engineering; Kemiteknik;

    Sammanfattning : This licentiate thesis presents experimental studies concerning two parts of the electrochemical cell in the chlorate process: a cathode and an anode.Newly synthesized MnOx electrodes were investigated for the cathodic reaction, hydrogen evolution reaction (HER) in the chlorate process. LÄS MER

  3. 2. Oxygen formation in the chlorate process and preparation and deactivation of ozone selective anodes

    Författare :Staffan Sandin; Ann M. Cornell; Paul Christensen; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATO; EOP; ozone; electrode preparation; elec- trode deactivation; hypochlorite; chlorate; oxygen; chromium VI ; sodium dichromate; electrocatalysis; catalysis; Chemical Engineering; Kemiteknik;

    Sammanfattning : This thesis presents experimental studies concerning two differ-ent electrolytic processes. One part deals with the electrochemicalformation of ozone and focuses on the preparation and deactiva-tion of a highly ozone-selective metal oxide anode (NATO - nickeland antimony doped tin oxide). LÄS MER

  4. 3. Energy efficiency in the sodium chlorate process: From electrocatalysis to pilot plant investigations

    Författare :Kristoffer Hedenstedt; Göteborgs universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Sodium chlorate; corrosion; mild steel; goethite; lepidocrocite; green rust; hypochlorite reduction; hydrogen evolution; in situ electrochemical Raman spectroscopy;

    Sammanfattning : Sodium chlorate is an important industrial chemical produced through an electrochemical manufacturing process. The global production rate is 3.6 million tons annually and consumes approximately 20 TWh of electrical power. The majority of the produced sodium chlorate is used as raw material to make chlorine dioxide for the bleaching of kraft pulp. LÄS MER

  5. 4. Mathematical modelling and experimental simulation of chlorate and chlor-alkali cells

    Författare :Philip Byrne; KTH; []
    Nyckelord :chlorate; chlor-alkali; current density distribution; current distribution; potential distribution; hydrodynamic behaviour; electrolysis; bubble-evolution;

    Sammanfattning : The production of chlorate, chlorine and sodium hydroxiderelies heavily on electrical energy, so that savings in thisarea are always a pertinent issue. This can be brought aboutthrough increased mass transfer of reacting species to therespective electrodes, and through increased catalytic activityand uniformity of current density distribution at theseelectrodes. LÄS MER

  7. 5. Electrochemical Investigations of Water and Hypochlorite Reduction on a-and y-FeOOH

    Författare :Kristoffer Hedenstedt; Göteborgs universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Sodium chlorate; corrosion; electrodeposition; goethite; lepidocrocite; hypochlorite reduction; hydrogen evolution;

    Sammanfattning : The cathodes in the electrochemical cells used for production of sodium chlorate process are made from mild steel. Due to the harsh environment in the chlorate cell, with oxidative species such as chlorate and hypochlorous acid, the cathodes corrodes. This corrosion might be beneficial, leading to surface enlargement and lower potential. LÄS MER