Sökning: "chromate"

Visar resultat 1 - 5 av 14 avhandlingar innehållade ordet chromate.

  1. 1. Alkali Induced High Temperature Corrosion of Stainless Steel - Experiences from Laboratory and Field

    Författare :Jesper Pettersson; Chalmers University of Technology; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; KCl; 304L; Biomass; Corrosion; Chlorine; Chromate; Waste; Deposit;

    Sammanfattning : The high temperature corrosion of steam superheaters is a major obstacle that has to be overcome in order to increase the electricity generating efficiency of power boilers burning biomass or waste. This thesis addresses this issue by a combination of well-controlled model experiments in the laboratory and short and long term field exposures using cooled probes in full-scale biomass and waste fired boilers. LÄS MER

  2. 2. Critical potential and oxygen evolution of the chlorate anode

    Författare :Linda Nylén; Göran Lindbergh; Yohannes Kiros; KTH; []
    Nyckelord :ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; chlorate; chloride oxidation; oxygen evolution; critical anode potential; chromate; DSA; mass transport; RDE; Chemical engineering; Kemiteknik;

    Sammanfattning : In the chlorate process, natural convection arises thanks to the hydrogen evolving cathode. This increases the mass transport of the different species in the chlorate electrolyte. There is a strong connection between mass transport and the kinetics of the electrode reactions. LÄS MER

  3. 3. Influence of the electrolyte on the electrode reactions in the chlorate process

    Författare :Linda Nylén; Göran Lindbergh; Ann Cornell; Mårten Behm; Geoeff H Kelsall; KTH; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Chlorate; chloride oxidation; critical anode potential; chromate; DSA; hydrogen evolution; iron; mass transport; oxygen evolution; REM; RDE; steel; Electrochemistry; Elektrokemi;

    Sammanfattning : The chlorate process is very energy intensive and a major part of the production costs are for electrical energy. Since the electricity prices are constantly increasing and may also vary periodically, the chlorate plants may be forced to adjust their production rate to the price at each moment in order to minimise their costs. LÄS MER

  4. 4. Activated Cathodes for the Hydrogen Evolution Reaction in Chlorate Manufacture

    Författare :Ann Cornell; Daniel Simonssom; KTH; []
    Nyckelord :chlorate; cathode; ruthenium dioxide; chromate;

    Sammanfattning : .... LÄS MER

  5. 5. Efficiency and Selectivity in the Chlorate Process

    Författare :Aleksandra Lindberg; Ann Cornell; Susanne Holmin; Eva Blomberg; KTH; []
    Nyckelord :ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; electrolysis; chlorate process; anodes; cathodes; selectivity; chromate; chromium VI ; DSA; HER; OER; ClER; oxygen; chlorate; hypochlorite; electrocatalysis; catalysis; Chemical Engineering; Kemiteknik;

    Sammanfattning : This licentiate thesis presents experimental studies concerning two parts of the electrochemical cell in the chlorate process: a cathode and an anode.Newly synthesized MnOx electrodes were investigated for the cathodic reaction, hydrogen evolution reaction (HER) in the chlorate process. LÄS MER