Sökning: "inclusion complexes"

Visar resultat 6 - 10 av 33 avhandlingar innehållade orden inclusion complexes.

1. 6. NMR Studies of Inclusion Compounds

   Författare :Sahar Nikkhou Aski; Jozef Kowalewski; Pierre Mutzenhardt; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NMR; 13C spin relaxation; PFGNMR; Kinetics; Correlation time; Physical chemistry; Fysikalisk kemi; Physical Chemistry; fysikalisk kemi;

   Sammanfattning : This thesis presents the application of some of the NMR methods in studying host-guest complexes, mainly in solution. The general focus of the work is on investigating the reorientational dynamics of some small molecules that are bound inside cavities of larger moieties. LÄS MER

3. 7. Chloromethane Complexation by Cryptophanes : Host-Guest Chemistry Investigated by NMR and Quantum Chemical Calculations

   Författare :Zoltan Takacs; Jozef Kowalewski; Mikael Akke; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Host–guest complexes; inclusion phenomenon; cryptophanes; NMR; kinetics; activation energy; dipolar interaction; exchange; quantum chemical optimization; calculated chemical shifts; NOESY; cavity size; fysikalisk kemi; Physical Chemistry;

   Sammanfattning : Host–guest complexes are widely investigated because of their importance in many industrial applications. The investigation of their physico–chemical properties helps understanding the inclusion phenomenon. The hosts investigated in this work are cryptophane molecules possessing a hydrophobic cavity. LÄS MER

4. 8. NMR Investigations of Host-Guest Complexes and Their Dynamic Properties

   Författare :Zdenek Tosner; Jozef Kowalewski; Josef Stepanek; Klaus Muller; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; supramolecular chemistry; host-guest complexes; non-covalent interactions; nuclear magnetic resonance; molecular motion; C-13 relaxation; deuterium NMR; dipolar recoupling; Physical chemistry; Fysikalisk kemi;

   Sammanfattning : This thesis discusses several different methods offered by solution and solid state nuclear magnetic resonance for investigation of host-guest complexes and their constituents. The presented methods were used especially (but not exclusively) to address rotational dynamics of the bound guest in different molecular systems. LÄS MER

5. 9. Cofinality Properties of Categories of Chain Complexes

   Författare :Fredrik Nordström; Wojciech Chachólski; Kathryn Hess; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; MATHEMATICS; MATEMATIK;

   Sammanfattning : This thesis treats a family of categories, the chain categories of an A-module M, and functors indexed by them. Among the chain categories are two classical constructions; the category of finitely generated projective Amodules, and the category of finitely generated free A-modules, here denoted by P0(0) and Sing(0) respectively. LÄS MER

7. 10. NMR Diffusion Studies of Association in Surfactant Systems Inclusion Complexes, Micellar Solutions and Microemulsions

   Författare :Markus Nilsson; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; host-guest complexation; gemini surfactant; cyclodextrin; bolaform surfactant; self-diffusion NMR; pluronic; bicontinuous microemulsion; polydispersity; boosting effect;

   Sammanfattning : The aim of this thesis has been to investigate self-diffusion behavior of host-guest complex, microemulsion and polymer solution. Pulsed Field Gradient NMR (PFG-NMR) was shown to provide detailed molecular information in all system studied. LÄS MER