Sökning: "host-guest system"

Visar resultat 1 - 5 av 11 avhandlingar innehållade orden host-guest system.

  1. 1. NMR Investigations of Host-Guest Complexes and Their Dynamic Properties

    Författare :Zdenek Tosner; Jozef Kowalewski; Josef Stepanek; Klaus Muller; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; supramolecular chemistry; host-guest complexes; non-covalent interactions; nuclear magnetic resonance; molecular motion; C-13 relaxation; deuterium NMR; dipolar recoupling; Physical chemistry; Fysikalisk kemi;

    Sammanfattning : This thesis discusses several different methods offered by solution and solid state nuclear magnetic resonance for investigation of host-guest complexes and their constituents. The presented methods were used especially (but not exclusively) to address rotational dynamics of the bound guest in different molecular systems. LÄS MER

  2. 2. Host-Guest Interactions for Structural Analysis of Organic Molecules : Development of new Tools for Stereochemical Characterization

    Författare :Sandra Olsson; Adolf Gogoll; Kari Rissanen; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; metalloporphyrins; host-guest systems; bis-porphyrin tweezers; stiff stilbene macrocycles; organic synthesis; porphyrin binding studies; NMR; ECCD; Chemistry with specialization in Organic Chemistry; Kemi med inriktning mot organisk kemi;

    Sammanfattning : The focus of this thesis is on the development of molecular tweezers as host-guest systems for stereochemical characterization of small organic molecules.There are two central problems to stereochemical characterization of small molecules. LÄS MER

  3. 3. Bicyclo[3.3.1]nonanes as Scaffolds in Supramolecular Chemistry : From Host-Guest Systems to Hydrogen-Bonded Aggregates

    Författare :Anna Lidskog; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; supramolecular chemistry; host-guest system; non-covalent interactions; hydrogen bonding; aromatic interactions; electrostatic interactions; synthetic receptors; self-assembly; nanotubes;

    Sammanfattning : This thesis describes the use of bicyclo[3.3.1]nonane and its heteroanalogue 1,5- diazabicyclo[3.3. LÄS MER

  4. 4. Accurate Force Fields for Spectroscopic Studies of Protein–Ligand Interactions and Self-Assembly Structures

    Författare :Yogesh Todarwal; Patrick Norman; Daniel Escudero; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Molecular Dynamics Simulations; Force Field Parametrization; Density Functional Theory; Host-Guest Chemistry; Self-Assembly Systems; Neurodegenerative Diseases; Supramolecular Chemistry; Fluorescent Ligands; Oligothiophenes; Cyclonaphthodithiophene Diimides; Sulfonimidamide Organogelators; Helicenes.; Theoretical Chemistry and Biology; Teoretisk kemi och biologi;

    Sammanfattning : The computational prediction of complex molecular behaviors is an essen- tial component of modern chemistry, as it provides a faster and more cost- effective way to explore molecular interactions that may be difficult or even impossible to study experimentally. Molecular dynamics (MD) simulations of- ten serve as a valuable tool for such predictions; however, their accuracy is inherently dependent on the force field (FF) parameters employed. LÄS MER

  5. 5. NMR Diffusion Studies of Association in Surfactant Systems Inclusion Complexes, Micellar Solutions and Microemulsions

    Författare :Markus Nilsson; Fysikalisk kemi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; host-guest complexation; gemini surfactant; cyclodextrin; bolaform surfactant; self-diffusion NMR; pluronic; bicontinuous microemulsion; polydispersity; boosting effect;

    Sammanfattning : The aim of this thesis has been to investigate self-diffusion behavior of host-guest complex, microemulsion and polymer solution. Pulsed Field Gradient NMR (PFG-NMR) was shown to provide detailed molecular information in all system studied. LÄS MER