Sökning: "grafting chemistry"

Visar resultat 1 - 5 av 50 avhandlingar innehållade orden grafting chemistry.

1. 1. Porous polymeric materials for chromatography : Synthesis, functionalization and characterization

   Författare :Emil Byström; Knut Irgum; Camilla Viklund; Solomon Tesfalidet; Klaus K Unger; Umeå universitet; []
   Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; porous polymer monolith; pore size distribution; nitrogen sorptiometry; mercury intrusion porosimetry; scanning and transmission electron microscopy; plasma functionalization; Analytical chemistry; Analytisk kemi; Separation methods; Separationsmetoder; Polymer chemistry; Polymerkemi; analytisk kemi; Analytical Chemistry;

   Sammanfattning : Background: Separation science is heavily reliant on materials to fulfill ever more complicated demands raised by other areas of science, notably the rapidly expanding molecular biosciences and environmental monitoring. The key to successful separations lies in a combination of physical properties and surface chemistry of stationary phases used in liquid chromatographic separation, and this thesis address both aspects of novel separation materials. LÄS MER

3. 2. Covalent Vapor-Phase Grafting of Degradable Polymers

   Författare :Martina Källrot; Ann-Christine Albertsson; Maria Nowokowska; KTH; []
   Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Vapor-phase grafting; covalent surface modification; functionalization; solvent-free grafting; sub-micron patterned topography; scaffolds; degradable polymers; poly L-lactide ; poly ε-caprolactone ; poly trimethylene carbonate ; poly L-lactide-co-glycolide ; poly 1; 5-dioxepan-2-one-co-L-lactide ; poly ε-caprolactone-co-L-lactide ; N-vinylpyrrolidone; maleic anhydride; acrylamide; acrylic acid; hyaluronic acid; in vitro degradation; Gasfasympning; kovalent ytmodifiering; funktionalisering; lösningsmedelsfri ympning; sub-micrometer mönstrad topografi; nedbrytbara polymerer; poly L-laktid ; poly ε-kaprolakton ; poly trimetylen karbonat ; poly L-laktid-co-glykolid ; poly 1; 5-dioxepan-2-one-co-L-laktid ; poly ε-kaprolakton-co-L-laktid N-vinylpyrrolidon; maleinsyraanhydrid; akrylamid; akrylsyra; hyaluronsyra; in vitro nedbrytning; Polymer chemistry; Polymerkemi;

   Sammanfattning : Gasfasympning är en del i den moderna strategin för optimering av den molekylära designen av biomaterial. Kovalent ytmodifiering med hydrofila vinylmonomerer och koppling med bioaktiva grupper används för att öka biokompatibiliteten och bioaktiviteten hos biomaterialen.. LÄS MER

4. 3. Tailoring Surface Properties of Bio-Fibers via Atom Transfer Radical Polymerization

   Författare :Josefina Lindqvist; Eva Malmström; Steven Rannard; KTH; []
   Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; cellulose; bio-fiber; atom transfer radical polymerization; surface modification; grafting; polymer brushes; functional surfaces; superhydrophobic; stimuli-responsive; Polymer chemistry; Polymerkemi;

   Sammanfattning : The potential use of renewable, bio-based polymers in high-technological applications has attracted great interest due to increased environmental concern. Cellulose is the most abundant biopolymer resource in the world, and it has great potential to be modified to suit new application areas. LÄS MER

5. 4. Polymer Nanocomposites in Thin Film Applications

   Författare :Linda Fogelström; Anders Hult; José M. Kenny; KTH; []
   Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Nanocomposites; hyperbranched polymers; montmorillonite; clay nanoparticles; exfoliated; coatings; crosslinking; TEM; XRD; mechanical properties; thermal properties; cellulose nanofibers; Atom Transfer Radical Polymerization; Ring-Opening Polymerization; poly ε-caprolactone ; surface modification; grafting; interfacial adhesion; Polymer chemistry; Polymerkemi;

   Sammanfattning : The introduction of a nanoscopic reinforcing phase to a polymer matrix offers great possibilities of obtaining improved properties, enabling applications outside the boundaries of traditional composites. The majority of the work in this thesis has been devoted to polymer/clay nanocomposites in coating applications, using the hydroxyl-functional hyperbranched polyester Boltorn® as matrix and montmorillonite clay as nanofiller. LÄS MER

7. 5. Tuning Properties of Surfaces and Nanoscopic Objects using Dendronization and Controlled Polymerizations

   Författare :Emma Östmark; Eva Malmström; Heikki Tenhu; KTH; []
   Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Dendrimers; dendronized polymers; cellulose; Atom Transfer Radical Polymerization; Ring-Opening Polymerization; surface modification; grafting; superhydrophobic; amphiphilic polymer; block copolymer; Atomic Force Microscopy; Polymer chemistry; Polymerkemi;

   Sammanfattning : In this study, dendronization and grafting via controlled polymerization techniques, atom transfer radical polymerization (ATRP) and ring-opening polymerization (ROP), have been explored. Modification of surfaces and cellulose using these techniques, which enable grafting of well-defined polymer architectures, has been investigated. LÄS MER