Sökning: "fluxional behavior"
Hittade 2 avhandlingar innehållade orden fluxional behavior.
1. Coordination of Phosphine-Thioether Ligands to Low-valent Metal Centers
Sammanfattning : The reactivity of the phosphine-thioether ligands bis(2-diphenylphosphino) ethylthio)ethane (PSSP), bis(2-(diphenylphosphino) ethyl)sulfane (PSP), PPh2CH2CH2SMe (PS), PPh2(o-C6H4SMe (PortoS), and PPh(o-C6H4SMe)2 (PSS) towards low-valent carbonyl clusters has been studied. In all structurally characterized clusters, the ligand donor atoms are terminally coordinated. LÄS MER
2. Investigation of Coordination Modes of Organosulfur Ligands to osmium and Rhodium Carbonyl Clusters- Possible Relevance to Hydrodesulfurization Reactions
Sammanfattning : The coordination and fundamental transformations of organosulfur compounds to polynuclear metal complexes has been studied as models for possible surface species in industrial HDS processes. Reactions between [Os3(CO)11(NCMe)] and various thiols have been studied by UV-Vis, IR and NMR spectroscopy and all experimental findings indicate that the reactions proceed via a two-step consecutive process involving the intermediate [Os3(CO)11(RSH)], which contains an agostic Os-H-S interaction, and which leads to the formation of the final product [Os3(CO)10(m-H)(m-SR)]. LÄS MER